Twisted Aromatic Frameworks: Readily Exfoliable and Solution-Processable Two-Dimensional Conjugated Microporous Polymers

Marco, A. Belen; Cortizo Lacalle, Diego; Pérez Miqueo, Iñigo; Valenti, Giovanni; Boni, Alessandro; Plas, Jan; Strutynski, Karol; De Feyter, Steven; Paolucci, Francesco; Montes Ramírez, Mario; Khlobystov, Andrei N.; Melle Franco, Manuel; Mateo Alonso, Aurelio

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Date

2017

Author

Marco, A. Belen

Cortizo Lacalle, Diego

Pérez Miqueo, Iñigo

Valenti, Giovanni

Boni, Alessandro

Plas, Jan

Strutynski, Karol

De Feyter, Steven

Paolucci, Francesco

Montes Ramírez, Mario

Khlobystov, Andrei N.

Melle Franco, Manuel

Mateo Alonso, Aurelio

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Estadisticas en RECOLECTA
(LA Referencia)

Angewandte Chemie-International Edition 56(24) : 6946-6951 (2017)

URI

http://hdl.handle.net/10810/27674

Abstract

Twisted two-dimensional aromatic frameworks have been prepared by overcrowding the nodes with bulky and rigid substituents. The highly distorted aromatic framework with alternating out-of-plane substituents results in diminished interlayer interactions that favor the exfoliation and dispersion of individual layers in organic media.

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This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.

Except where otherwise noted, this item's license is described as This is an open access article under the terms of the Creative Commons Attribution‐NonCommercial License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.