Mikrouhinen bidezko beroketaren onurak koloratzailez dopaturiko material hibridoen sintesian
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Date
2020Author
Oliden Sánchez, Ainhoa
Sola Llano, Rebeca
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Ekaia 37 : 117-128 (2020)
Abstract
Due to the huge steps forward the technology has undergone, more and more sophisticated properties are required in systems to accomplish today's needs, and often these features can hardly be achieved with conventional materials. In order to tackle this problem, hybrid materials have entered with great force, which can have new and improved features. Hence, inorganic supports that include photoactive organic molecules are very interesting, because they provide rigidity, protection and order to organic molecules, reinforcing the properties of chromophores. This paper describes the development of LDS 730 hemicyanine embedded in MgAPO-5 zeolite, an outstanding material that emits electromagnetic radiation in the near infrared region. In addition to outlining technological applications, the photophysical and structural properties of this material have been analyzed together with two types of heating synthesis processes: the conventional and microwave oven-synthesis have been compared, highlighting the advantages of the last one.; Teknologiak jasan dituen aurrerapauso ikaragarriak direla eta, gero eta propietate konplexuagoak dituzten sistemak behar dira gaur egungo beharrak asetzeko, eta maiz, ezaugarri horiek nekez lor daitezke ohiko materialekin. Arazo honi aurre egiteko, ezaugarri berri eta hobetuak erakusten dituzten material hibridoek indar handia hartu dute. Honen harian, molekula organiko fotoaktiboak barne hartzen dituzten euskarri ez-organikoak interesgarriak dira, molekula organikoei zurruntasuna, babesa eta ordena eskaintzen dietelako, kromoforoen propietateak sendotuz. Lan honetan, berebiziko interesa duen eta infragorri hurbileko eremuan erradiazio elektromagnetikoa igortzen duen material baten garapena deskribatzen da, LDS 730 hemizianina MgAPO-5 material zeolitikoan kapsulatuz. Aplikazio teknologikoak gogoan izanda, propietate fotofisikoak eta estrukturalak aztertzeaz gain, sintesi prozesua ere ikertu da, materiala bi beroketa metodo desberdinen bidez lortuz. Horrela, ohiko labearen eta mikrouhin labearen bidezko sintesiak konparatu dira, azken honen abantailak goraipatuz.