dc.contributor.author | Errandonea Martín, Jon | |
dc.contributor.author | Garate Olave, Idoia | |
dc.contributor.author | Roda Robles, María Encarnación | |
dc.contributor.author | Cardoso Fernandes, Joana | |
dc.contributor.author | Lima, Alexandre | |
dc.contributor.author | dos Anjos Ribeiro, Maria | |
dc.contributor.author | Teodoro, Ana Claudia | |
dc.date.accessioned | 2022-12-05T18:16:44Z | |
dc.date.available | 2022-12-05T18:16:44Z | |
dc.date.issued | 2022-11 | |
dc.identifier.citation | Ore Geology Reviews 150 : (2022) // Article ID 105155 | es_ES |
dc.identifier.issn | 0169-1368 | |
dc.identifier.issn | 1872-7360 | |
dc.identifier.uri | http://hdl.handle.net/10810/58676 | |
dc.description.abstract | Fluid-assisted mass transfer and re-equilibration of mineral phases are common consequences of metasomatism associated with igneous intrusions. The addition and/or removal of chemical components in these environments may result in the generation of metasomatic aureoles, which can be recognized by their mineralogy and geochemistry. Due to an increasing demand for critical raw materials used in green energy technologies, rare-element granitic pegmatites have seen renewed interest in the mineral exploration industry. Granitic pegma-tites represent potential sources of critical commodities and geochemical studies of their related aureoles help to advance techniques in exploration targeting. Moreover, the role and timing of fluid exsolution during magma-tic-hydrothermal evolution in granitic-pegmatitic systems and concomitant element mobility remain highly debated.We present a prospect-scale systematic study of geochemical haloes generated by LCT (Li-Cs-Ta) family pegmatite dykes from the Fregeneda-Almendra Pegmatite Field, in the Central Iberian Zone of the Iberian Massif (Spain and Portugal). To understand the magnitude of metasomatic processes linked to these intrusions, we performed whole-rock mass-balance calculation of element gains and losses in variably metasomatized psam-mitic and pelitic host metasediments. The results show that F, B, Li, Rb, Cs, Sn, Be, Tl, As, W and S (+/- Mo, Ta) were carried by early exsolved and expelled aqueous fluids. The first evidence of element enrichment is recorded at distances of 4-5 times the thickness of the dykes, with exponentially increasing gains of those fluid-mobile elements proximal to the pegmatite margin. Enrichments that were detected farthest from the pegmatite mar-gins were those of Li and Cs, followed by Rb and, to a lesser extent, Sn, F, B, Be, and Tl. The most evolved (fractionated) aplite-pegmatites generated the broadest haloes, with concentrations higher than 200 ppm Li, 30 ppm Cs, 300 ppm Rb, and 15 ppm Sn in the metasediments indicating proximity to a mineralized dyke. In addition, absolute gains of up to-4000 ppm Li,-1300 ppm Cs,-1300 ppm Rb, and 170 ppm Sn in the host rocks could point to the presence of superimposed haloes from multiple evolved dykes. | es_ES |
dc.description.sponsorship | Financial support was provided by the European Commission's Horizon 2020 Innovation Programme [grant agreement No 869274, project GREENPEG: New Exploration Tools for European Pegmatite Green-Tech Resources]; grant RTI2018-094097-B-100 funded by MCIN/AEI/10.13039/501100011033 and, by "ERDF A way of making Europe"; and the University of the Basque Country UPV/EHU [grant GIU18/084]. The authors are grateful to Kathryn M. Goodenough, an anonymous reviewer, and Tania Martins for their constructive comments, which have improved considerably the quality of the manuscript. Editorial handling and helpful suggestions by Franco Pirajno and Allen K. Andersen are also acknowledged. The. Work of I. Garate-Olave has been supported also by the UPV/EHU by means of the "Convocatoria de contratacion para la especializacion de personal investigador doctor en la UPV/EHU 2019". Financial support provided by FCT- Fundacao para a Ciencia e a Tecnologia, I.P., with the ERA-MIN/0001/2017 - LIGHTS project and through the FCT project UIDB/04683/2020 and UIDP/04683/2020 - ICT (Institute of Earth Sciences) is recognized. J. Cardoso - Fernandes has been financially supported within the compass of a Ph.D. Thesis, ref. SFRH/BD/136108/2018, by Portuguese national funds from MCTES through FCT, and co-financed by the European Social Fund (ESF) through POCH - Programa Operacional Capital Humano - and NORTE 2020 regional program. | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation | info:eu-repo/grantAgreement/EC/H2020/869274 | es_ES |
dc.relation | info:eu-repo/grantAgreement/MICIU/RTI2018-094097-B-100 | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/3.0/es/ | * |
dc.subject | lithium pegmatite | es_ES |
dc.subject | metasomatism | es_ES |
dc.subject | geochemical halo | es_ES |
dc.subject | lithogeochemistry | es_ES |
dc.subject | psammitic and pelitic metasediments | es_ES |
dc.subject | geochemical exploration | es_ES |
dc.title | Metasomatic effect of Li-bearing aplite-pegmatites on psammitic and pelitic metasediments: Geochemical constraints on critical raw material exploration at the Fregeneda-Almendra Pegmatite Field (Spain and Portugal) | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2022 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/). | es_ES |
dc.rights.holder | Atribución 3.0 España | * |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S0169136822004632?via%3Dihub | es_ES |
dc.identifier.doi | 10.1016/j.oregeorev.2022.105155 | |
dc.contributor.funder | European Commission | |
dc.departamentoes | Geología | es_ES |
dc.departamentoeu | Geologia | es_ES |