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M(C6H16N3)2(VO3)4 as heterogeneous catalysts. Study of three new hybrid vanadates of cobalt(II), nickel(II) and copper(II) with 1-(2-aminoethyl)piperazonium.
(Royal Society of Chemistry, 2011-10-14)
Three new hybrid vanadates have been synthesized under hydrothermal conditions with the formula M(C6H16N3)2(VO3)4, where M= Co(II), Ni(II) and Cu(II). The structural analyses show that the phases are isostructural and ...
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ...
Hydrothermal Synthesis and Study of Inorganic-Organic Hybrid Vanadate of Nickel(II) Coordination Complex with Pyrazine, Ni3(C4H4N2)3(V8O23)
The three-dimensional hybrid compound Ni3(C4H4N2)3(V8O23) has been synthesized by mild hydrothermal methods under autogenous pressure at 170 ºC, together with another hybrid phase, Ni2(C4H4N2)(V4O12)(H2O)2. The isolation ...
Self-assembly of iron TCPP (meso-tetra(4-carboxyphenyl)porphyrin) into a chiral 2D coordination polymer
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of high-dimensional coordination polymers. In this work, a new chiral Fe-TCPP (TCPP is ...