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dc.contributor.authorBazán Blau, Begoña del Pilar ORCID
dc.contributor.authorBarandika Argoitia, Miren Gotzone ORCID
dc.contributor.authorLlano Tomé, Francisco
dc.contributor.authorUrtiaga Greaves, Miren Karmele ORCID
dc.contributor.authorArriortua Marcaida, María Isabel ORCID
dc.date.accessioned2016-02-16T17:19:03Z
dc.date.available2016-02-16T17:19:03Z
dc.date.issued2016-02-16
dc.identifier.urihttp://hdl.handle.net/10810/17356
dc.description.abstract[EN] Combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce solid coordination frameworks (SCF) which are crystalline materials based on connections between metal ions through organic ligands. In this sense, combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce extended structures. In this context, this work is focused on two novel CuII-based SCFs exhibiting PDC (2,5-pyridinedicarboxylate) and bpa (1,2-di(4-pyridyl)ethane), being the first structures reported in literature containing both ligands. Chemical formula are [Cu2[(PDC)2(bpa)(H2O)2]•3H2O•DMF (1), and [Cu2(PDC)2(bpa)(H2O)2]•7H2O (2), where DMF is dimethylformamide. Compounds 1 and 2 have been characterized by means of XRD, IR, TG/DTG, and DTA analysis.en
dc.description.sponsorshipMinisterio de Economía y Competitividad (MAT2013-42092-R, FEDER MAT2010-21342-C02-01), Gobierno Vasco (Basque University System Research Group, IT-630-13, UPV/EHU (UFI 11/15), Ministerio de Ciencia e Innovación(BES-2011-045781).es
dc.language.isoenges
dc.relationinfo:eu-repo/grantAgreement/MINECO/MAT2013-42092-R
dc.relationinfo:eu-repo/grantAgreement/MINECO/MAT2010-21342-C02-01
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/*
dc.subjectsolid coordination networksen
dc.subjectMOFsen
dc.subjectX-ray crystal structureen
dc.titleSynthesis and structural characterisation of [Cu2[(PDC)2(bpa)(H2O)2]•nH2O•mDMF (n=3 and m=1 for 1, n=7 and m=0 for 2, PDC=2,5-pyrindinedicarboxylate and bpa= 1,2-di(4-pyridil)ethane))es
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holderAttribution-NonCommercial-NoDerivatives 4.0 International*
dc.departamentoesQuímica inorgánicaes_ES
dc.departamentoeuKimika ez-organikoaes_ES


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Attribution-NonCommercial-NoDerivatives 4.0 International
Except where otherwise noted, this item's license is described as Attribution-NonCommercial-NoDerivatives 4.0 International