BackBrowsing Artículos by Author "Rodríguez-Diéguez, Antonio"
Now showing items 1-7 of 7
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A Luminescent MOF Based on Pyrimidine-4,6-dicarboxylate Ligand and Lead(II) with Unprecedented Topology
(MDPI, 2023-10-13)In the present work, we report on a 3D MOF of {[Pb5(μ3-OH)(μ3-NO3)3(μ6-pmdc)3]·H2O}n formula (pmdc = pyrimidine-4,6-dicarboxylate) synthesized by an oven-heated, solvent-free procedure. The large connectivity afforded by ... -
A Mixed Heterobimetallic Y/Eu-MOF for the Cyanosilylation and Hydroboration of Carbonyls
; ; ; ; ; Seco Botana, José Manuel
; ; (MDPI, 2022-03-06)
Herein, to the best of our knowledge, the first heterobimetallic Y/Eu porous metal–organic framework (MOF), based on 3-amino-4-hydroxybenzoic acid (H2L) ligand, with the following formulae {[Y3.5Eu1.5L6(OH)3(H2O)3]·12DMF}n ... -
A Potassium Metal-Organic Framework based on Perylene- 3,4,9,10-tetracarboxylate as Sensing Layer for Humidity Actuators
Seco Botana, José Manuel; San Sebastián Larzabal, Eider ; ; ; ; ; ; ; Gómez-Ruiz, Santiago ; ; ; (Nature Publishing, 2018-09-26)
We have synthesized a novel three-dimensional metal-organic-framework (MOF) based on the perylene-3,4,9,10-tetracarboxylate linker and potassium as metallic centre. We report the formation of this K-based MOF using ... -
Exploring the Slow Magnetic Relaxation of a Family of Photoluminescent 3D Lanthanide–Organic Frameworks Based on Dicarboxylate Ligands
; ; ; ; ; Seco Botana, José Manuel; ; (MDPI, 2021-03-16)
A family of metal–organic frameworks with general formula {[Nd2(ant)2((NH2)2-bdc)(DMF)4]·2DMF}n (1) and {[Ln2(ant)2((NH2)2-bdc)(DMF)4]·2DMF·2H2O}n (Ln = Tb (2), Ho (3), and Er (4)) has been obtained from reactions between ... -
Luminescence and Magnetic Properties of Two Three -Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4 '-Dicarboxylic Linker
Fernández, Belén; Oyarzabal Epelde, Itziar; Seco Botana, José Manuel; San Sebastián Larzabal, Eider ; Fairen-Jiménez, David; Gómez-Ruiz, Santiago ; Salinas-Castillo, Alfonso; Calahorro, Antonio J.; Rodríguez-Diéguez, Antonio (MDPI, 2016-02)
We report the in situ formation of two novel metal-organic frameworks based on terbium and dysprosium ions using azobenzene-4,4-dicarboxylic acid (H(2)abd) as ligand, synthesized by soft hydrothermal routes. Both materials ... -
Magnetic and Luminescent Properties of Isostructural 2D Coordination Polymers Based on 2-Pyrimidinecarboxylate and Lanthanide Ions
; ; ; ; Seco Botana, José Manuel; ; ; (MDPI, 2020-07-02)
A couple of isostructural coordination polymers with the general formula [Ln4(pymca)4(AcO)8]n have been obtained from reactions between pyrimidine-2-carboxylate (pymca) ligand and rare-earth ions (Ln = Dy (1), Nd (2)). ... -
Selectivity of Relative Humidity Using a CP Based on S-Block Metal Ions
(MDPI, 2022-02-21)Herein, we present the syntheses of a novel coordination polymer (CP) based on the perylene-3,4,9,10-tetracarboxylate (pery) linkers and sodium metal ions. We have chosen sodium metal center with the aim of surmising the ...