Browsing Artículos by Author "Sola Llano, Rebeca"
Now showing items 1-15 of 15
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A Malonyl-Based Scaffold for Conjugatable Multivalent Carbohydrate-BODIPY Presentations
Uriel, Clara; Sola Llano, Rebeca; Bañuelos Prieto, Jorge ; Gómez López, Ana María; López Pérez, José Cristóbal (MDPI, 2019-06-01)A concise synthetic route from methylmalonate to a tetravalent aliphatic scaffold has been developed. The ensuing tetra-tethered derivative is equipped with two hydroxyl groups, as well as orthogonal alkene and alkyne ... -
A versatile synthetic approach to design tailor-made push-pull chromophores with intriguing and tunable photophysical signatures
Belmonte-Vázquez, José L.; Sola Llano, Rebeca; Bañuelos Prieto, Jorge ; Betancourt-Mendiola, Lourdes; Vázquez-Guevara, Miguel A.; López Arbeloa, Iñigo María; Peña Cabrera, Eduardo (Elsevier, 2017-08-12)Novel modified Biellmann BODIPYs were prepared using a C-H arylation reaction with in-situ formed aryldiazonium salts. The post-functionalization of the methylthio group of these derivatives was demonstrated in SNAr and ... -
AcetylacetonateBODIPY−biscyclometalated Iridium(III) complexes: effective strategy towards smarte fluorescentphotosensitizer agents
Palao, Eduardo; Sola Llano, Rebeca; Tabero, Andrea; Manzano Moro, Hegoi ; Agarrabeitia, Antonia R.; Villanueva, Angeles; López Arbeloa, Iñigo María; Martínez Martínez, Virginia ; Ortiz, María J. (Wiley-VCH GmbH, Weinheim, 2017-05-19)Biscyclometalated Ir(III) complexes involving BODIPYbased ancillary ligands, where the BODIPY unit is grafted to different chelating cores (acetylacetonate for Ir-1 and Ir-2, and bipyridine for Ir-3) by the BODIPY meso ... -
Catalyst-Free Amino-Yne Click Reaction: An Efficient Way for Immobilizing Amoxicillin onto Polymeric Surfaces
Sánchez Bodón, Julia; Díaz Galbarriatu, Maria; Sola Llano, Rebeca; Ruiz Rubio, Leire; Vilas Vilela, José Luis ; Moreno Benitez, María Isabel (MDPI, 2024-01-15)Surface modifications play a crucial role in enhancing the functionality of biomaterials. Different approaches can be followed in order to achieve the bioconjugation of drugs and biological compounds onto polymer surfaces. ... -
Confinement of a Styryl Dye into Nanoporous Aluminophosphates: Channels vs. Cavities
Oliden Sánchez, Ainhoa; Sola Llano, Rebeca; Pérez Pariente, Joaquín; Gómez Hortigüela, Luis; Martínez Martínez, Virginia (MDPI, 2024-03-22)Styryl dyes are generally poor fluorescent molecules inherited from their flexible molecular structures. However, their emissive properties can be boosted by restricting their molecular motions. A tight confinement into ... -
Enhanced Phosphorescence Emission by Incorporating Aromatic Halides into an Entangled Coordination Framework Based on Naphthalenediimide
Martínez Martínez, Virgina; Sola Llano, Rebeca; Furukawa, Shuhei; Takashima, Yohei; López Arbeloa, Iñigo; Kitagawa, Susumu (Wiley, 2014-08)Phosphorescence emission at room temperature is turned on in an entangled porous coordination polymer (PCP) with naphthalenediimide (NDI) as chromophore, by incorporating halogenated guests into the pores. The phosphorescent ... -
Exploiting the photophysical features of DMAN template in ITQ-51 zeotype in the search for FRET energy transfer
Oliden Sánchez, Ainhoa; Sola Llano, Rebeca; Pérez Pariente, Joaquín; Gómez Hortigüela, Luis; Martínez Martínez, Virginia (RSC, 2024-02)The combination between photoactive molecules and inorganic structures is of great interest for the development of advanced materials in the field of optics. Particularly, zeotypes with extra-large pore size are attractive ... -
Formation of a Nonlinear Optical Host–Guest Hybrid Material by Tight Confinement of LDS 722 into Aluminophosphate 1D Nanochannels
Sola Llano, Rebeca; Martínez Martínez, Virginia ; Fujita, Yasuhiko; Gómez Hortigüela, Luis; Alfayate, Almudena; Uji-i, Hiroshi; Fron, Eduard; Pérez Pariente, Joaquín; López Arbeloa, Iñigo (Wiley, 2016-09-15)In this work, hemicyanine dye LDS 722, is encapsulated into the 1-D elliptical nano-channels of MgAPO-11 aluminophosphate by crystallization inclusion method. The synthesis of the hybrid material has been optimized through ... -
Fully Functionalizable β,β'-BODIPY Dimer: Synthesis, Structure, and Photophysical Signatures
Arroyo-Córdoba, Ismael J.; Sola Llano, Rebeca; Epelde Elezcano, Nerea; López Arbeloa, Iñigo María; Martínez Martínez, Virginia ; Peña Cabrera, Eduardo (ACS, 2018-08-16)The versatility in the synthesis of BODIPY derivatives in terms of functionalization is further demonstrated. Particularly, in this work β−β’-BODIPY dimers with varied functional groups in the meso-positions were synthetized ... -
Highly Luminescent and Optically Switchable Hybrid Material by One Pot Encapsulation of Dyes into MgAPO-11 Unidirectional Nanopores
Martínez Martínez, Virginia ; García, Raquel; Gómez Hortigüela, Luis; Sola Llano, Rebeca; Pérez Pariente, Joaquín; López Arbeloa, Iñigo María (ACS, 2014-02-06)In this work a highly fluorescent hybrid material with strong anisotropic response is obtained by “one-pot” synthesis. The system is based on the “in situ” encapsulation of two chromophores, Acridine (AC) and Pyronine Y ... -
One-Directional Antenna Systems: Energy Transfer from Monomers to JAggregates within 1D Nanoporous Aluminophosphates
Sola Llano, Rebeca; Fujita, Yasuhiko; Gómez Hortigüela, Luis; Alfayate, Almudena; Uji-i, Hiroshi; Fron, Eduard; Toyouchi, Shuichi; Pérez Pariente, Joaquín; López Arbeloa, Iñigo María; Martínez Martínez, Virginia (ACS, 2017-10-01)A cyanine dye (PIC) was occluded into two 1D-nanopoporus Mg-containing aluminophosphates with different pore size (MgAPO-5 and MgAPO-36 with AFI and ATS zeolitic structure types, with cylindrical channels of 7.3 Å diameter ... -
Red haloBODIPYs as theragnostic agents: The role of the substitution at meso position
Prieto Montero, Ruth ; Prieto Castañeda, Alejandro; Katsumiti Kodo Filho, Alberto ; Sola Llano, Rebeca; Rodríguez Agarrabeitia, Antonia; Cajaraville Bereciartua, Miren Pilare ; Ortiz, María J.; Martínez Martínez, Virginia (Elsevier, 2022-01-30)Three different molecular designs based on BODIPY dye have been proposed as photosensitizers (PSs) for photodynamic therapy (PDT) by the inclusion of halogen atoms (Iodine) at 2,6-positions and with extended conjugation ... -
Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules
Sola Llano, Rebeca; Martínez Martínez, Virginia ; Furukawa, Shuhei; Takashima, Yohei; López Arbeloa, Iñigo María (MDPI, 2018-02)Taking advantage of the outstanding properties of a naphthalenediimide-based entangled porous coordination polymer, a simple strategy for the achievement of white light emission is herein presented. The dynamic structural ... -
Tuning the Photonic Behavior of Symmetrical bis-BODIPY Architectures: The Key Role of the Spacer Moiety
Oliden Sánchez, Ainhoa; Sola Llano, Rebeca; Bañuelos Prieto, Jorge ; García Moreno, Inmaculada; Uriel, Clara; López Pérez, José Cristóbal; Gómez López, Ana María (Frontiers Media, 2019-12)Herein we describe the synthesis, computationally assisted spectroscopy, and lasing properties of a new library of symmetric bridged bis-BODIPYs that differ in the nature of the spacer. Access to a series of BODIPY dimers ... -
White Light Emission by Simultaneous One Pot Encapsulation of Dyes into One-Dimensional Channelled Aluminophosphate
Sola Llano, Rebeca; Oliden Sánchez, Ainhoa; Alfayate, Almudena; Gómez Hortigüela, Luis; Pérez Pariente, Joaquín; Arbeloa López, María Teresa; Hofkens, Johan; Fron, Eduard; Martínez Martínez, Virginia (MDPI, 2020-06-16)By simultaneous occlusion of rationally chosen dyes, emitting in the blue, green and red region of the electromagnetic spectrum, into the one-dimensional channels of a magnesium-aluminophosphate with AEL-zeolitic type ...