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dc.contributor.advisorMielgo Vicente, María Antonia
dc.contributor.authorLarrea Peruchena, Ainhoa
dc.contributor.otherF. CIENCIAS QUIMICAS
dc.contributor.otherKIMIKA ZIENTZIEN F.
dc.date.accessioned2020-10-16T18:23:56Z
dc.date.available2020-10-16T18:23:56Z
dc.date.created2020-10-16
dc.identifier.urihttp://hdl.handle.net/10810/46992
dc.description.abstract[EU]Ondorengo Gradu Amaierako Proiektu hau Donostiako Kimika Zientzien Fakultateko Kimika Organikoa I Departamentuan burutu da, Antonia Mielgo Vicente irakasleak zuzendua. Proiektua kimika organikako alorrean kokatzen da, organokatalisi asimetrikoan hain zuzen. Honen helburu nagusia ureidopeptido motako katalizatzaile batzuk sintetizatzea izan da eta haien eraginkortasuna α-ordezkatutako nitroalkano eta α-hidroxienona baten arteko Michael erreakzio batean frogatzea. Lortutako emaitzek katalizatzaile onena pireno eta L-tert-leuzinatik eratorritakoa (C3) dela erakusten dute, erreakio-produktua %79 ee balioarekin lortuz.es_ES
dc.description.abstract[EN]The following project has been carried out in the Department of Organic Chemistry I at the Faculty of Chemistry in San Sebastian, under the guidance of professor Antonia Mielgo Vicente. The project is related to the field of organic chemistry and more specifically to the field of asymmetric organocatalysis. Its main purpose has been to sythesize new ureidopeptide like catalysts and check their efficiency in the asymmetric Michael reaction of a-branched nitroalkanes and a­ hydroxyenones. The results show that pyrene and L-tert-leucine derived catalyst (C3) is the best, as it provides the reaction product in 79% ee.
dc.language.isoeuses_ES
dc.rightsinfo:eu-repo/semantics/openAccess
dc.subjectkatalisi asimetrikoaes_ES
dc.subjectMichael erreakzioa
dc.subjectureidopeptidoak
dc.titleα-Ordezkatutako nitroalkanoen adizio konjokatuetarako ureidopeptido motako katalizatzaileen sintesiaes_ES
dc.typeinfo:eu-repo/semantics/bachelorThesis
dc.date.updated2018-02-13T08:36:19Z
dc.language.rfc3066es
dc.rights.holder© 2018, la autora
dc.identifier.gaurassign67368-763995


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