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Shape of Testosterone

dc.contributor.authorLeón Ona, Iker
dc.contributor.authorAlonso Alonso, Elena Rita
dc.contributor.authorMata, Santiago
dc.contributor.authorAlonso, José Luis
dc.date.accessioned2021-10-04T11:31:29Z
dc.date.available2021-10-04T11:31:29Z
dc.date.issued2021-07-29
dc.identifier.citationJournal of Physical Chemistry Letters 12(29) : 6983-6987 (2021)es_ES
dc.identifier.issn1948-7185
dc.identifier.urihttp://hdl.handle.net/10810/53218
dc.description.abstractWe have successfully characterized the structure of testosterone, one of the essential steroids, through high-resolution rotational spectroscopy. A single conformer has been detected, and a total of 404 transitions have been fitted, allowing a precise determination of the rotational constants. It allowed us to unravel that the isolated structure of testosterone adopts an extended disposition. The results obtained in this work highlight how using laser ablation techniques in combination with Fourier transform microwave techniques allow the study of large biomolecules or common pharmaceuticals. It is an important step toward studying relevant biomolecules and developing new analytical techniques with unprecedented sensitivity and resolution.es_ES
dc.description.sponsorshipThe financial fundings from the Ministerio de Ciencia e Innovacion (CTQ2016-76393-P and PID2019-111396GBI00), Junta de Castilla y Leon (Grants VA077U16 and VA244P2), and European Research Council under the European Union's Seventh Framework Programme (FP/2007-2013)/ERC-2013-SyG, Grant Agreement n. 610256 NANOCOSMOS, are gratefully acknowledged. E.R.A. acknowledges the Ministerio de Ciencia e Innovacion for a Juan de la Cierva postdoctoral grant (FJC2018-037320-I).es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/CTQ2016-76393-Pes_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/PID2019-111396GBI00es_ES
dc.relationinfo:eu-repo/grantAgreement/EC/FP7/610256es_ES
dc.relationinfo:eu-repo/grantAgreement/MICINN/FJC2018-037320-Ies_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectspectroscopyes_ES
dc.subjectrelaxationes_ES
dc.subjectconformerses_ES
dc.subjectcrystales_ES
dc.subjectspectraes_ES
dc.titleShape of Testosteronees_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holder2021 The Authors. Published by American Chemical Society. Attribution 4.0 International (CC BY 4.0) You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.es_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/acs.jpclett.1c01743es_ES
dc.identifier.doi10.1021/acs.jpclett.1c01743
dc.contributor.funderEuropean Commission
dc.departamentoesQuímica físicaes_ES
dc.departamentoeuKimika fisikoaes_ES


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2021 The Authors. Published by American Chemical Society. Attribution 4.0 International (CC BY 4.0) You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.
Except where otherwise noted, this item's license is described as 2021 The Authors. Published by American Chemical Society. Attribution 4.0 International (CC BY 4.0) You must give appropriate credit, provide a link to the license, and indicate if changes were made. You may do so in any reasonable manner, but not in any way that suggests the licensor endorses you or your use.