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Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
(MDPI (Multidisciplinary Digital Publishing Institute) Basel, Switzerland, 2015-04-15)
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ...
Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives
(RSC Publishing, 2015-05-07)
Compound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-benzenedicarboxylate and DMF is N,N-dimethylformamide) has been synthesized and structurally characterized by X-ray diffraction. It consists of Cu24-clusters ...