Now showing items 1-5 of 5
Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
(MDPI (Multidisciplinary Digital Publishing Institute) Basel, Switzerland, 2015-04-15)
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ...
Highly thermally stable heterogeneous catalysts: study of 0D and 3D porphyrinic MOFs
(The Royal Society of Chemistry, 2017-11-13)
Heterogeneous catalysts are a great bet for green chemistry in many industrial processes and, in the past decade, promising results have been achieved in order to improve the catalytic activity of Metal Organic Frameworks ...
Cationic Mn2+/H+ exchange leading a slow solid-state transformation of a 2D porphyrinic network at ambient conditions
Metalloporphyrins exhibit outstanding chemical, physical and biological properties in dissolution, however, it is a challenge to synthesize them as stable solid frameworks. Long-time stability is crucial for future ...
Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives
(RSC Publishing, 2015-05-07)
Compound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-benzenedicarboxylate and DMF is N,N-dimethylformamide) has been synthesized and structurally characterized by X-ray diffraction. It consists of Cu24-clusters ...
CuII-based metal-organic nanoballs for very rapid adsorption of dyes and iodine
(The Royal Society of Chemistry, 2016-02-03)
CuII nanoballs have been determined to be among the best MOPs (Metal–Organic Polyhedra) reported so far for the adsorption of small molecules, with the highlighting advantage of rapid kinetics, which focuses on their ...