Now showing items 1-6 of 6
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ...
Metalloporphyrin-based MOFs: new strategies for catalyst immobilization
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Cationic Mn2+/H+ exchange leading a slow solid-state transformation of a 2D porphyrinic network at ambient conditions
Metalloporphyrins exhibit outstanding chemical, physical and biological properties in dissolution, however, it is a challenge to synthesize them as stable solid frameworks. Long-time stability is crucial for future ...
Dehydration for a solid coordination network based on CuII-(py)2C(OH)2 trimers
Materials consisting of metal ions or clusters that are linked by polyfunctional organic ligands form networks of different dimensionalities. Their structural features, including large cavities and high surface areas, ...
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
(RSC Publishing, 2015-01-07)
During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ...
Fe−TPP Coordination Network with Metalloporphyrinic Neutral Radicals and Face-to-Face and Edge-to-Face π−π Stacking
(ACS Publications, 2013-06-25)
Compound ([FeTPPbipy]•)n (TPP = meso-tetraphenylporphyrin and bipy = 4,4′-bipyridine) is the first example of a Fe−TPP−bipy coordination network, and it consists of 1D polymers packed through face-to-face and edge-to-face ...