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Metalloporphyrin-based MOFs: new strategies for catalyst immobilization
(2016-04-25)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Theoretical and experimental absorption spectra study of [(FeTPPbipy]·)n provided by TD-DFT calculations
(2016-04-29)
Iron metalloporphyrins are paradigmatic examples of nanodevices used by natural systems like haemoglobin or cytochromes in oxygen transport, electron transfer and catalysis. Therefore, they can be thought to be developed ...
Characterization of cobalt based TPP-bipy coordination polymer
(2016-04-22)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Metalloporphyrin-based MOFs: First Cobalt Based TPPS-bipy Coordination Network
(2016-04-22)
Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ...
Crystal structure and characterization of a new μ-oxo bridged iron porphyrin
(2016-04-22)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Dehydration for a solid coordination network based on CuII-(py)2C(OH)2 trimers
(2016-04-22)
Materials consisting of metal ions or clusters that are linked by polyfunctional organic ligands form networks
of different dimensionalities. Their structural features, including large cavities and high surface areas, ...
Biomimetic catalysts based on metalloporphyrin MOFs
(2016-04-29)
During the past years, a great effort has been devoted to the anchoring of catalysts into MOFs in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using metalloporphyrins as ...
Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)
(2016-04-29)
Solid Coordination Frameworks (SCFs) have been widely explored on different catalytic reactions, and during the past years metalloporphyrins have been investigating in order to mimick it in the solid state their natural ...
Synthesis and structural characterisation of [Cu2[(PDC)2(bpa)(H2O)2]•nH2O•mDMF (n=3 and m=1 for 1, n=7 and m=0 for 2, PDC=2,5-pyrindinedicarboxylate and bpa= 1,2-di(4-pyridil)ethane))
(2016-02-16)
[EN] Combination of polycarboxylate anions and dipyridyl ligands is an effective strategy to produce solid coordination frameworks (SCF) which are crystalline materials based on connections between metal ions through organic ...
CuII-based metal-organic nanoballs for very rapid adsorption of dyes and iodine
(The Royal Society of Chemistry, 2016-02-03)
CuII nanoballs have been determined to be among the best MOPs (Metal–Organic Polyhedra) reported so far for the adsorption of small molecules, with the highlighting advantage of rapid kinetics, which focuses on their ...