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Self-assembly of metallated TPP porphyrin by external dipyridyl ligands
(2015-10-23)
Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ...
Auto-ensamblaje de unidades porfirínicas para la obtención de dispositivos supramoleculares
(2015-10-23)
Las entidades supramoleculares basadas en el auto-ensamblaje de metaloporfirinas son ejemplos paradigmáticos de la gran eficiencia de los nanodispositivos empleados por los seres vivos para el almacenamiento y el transporte ...
Functionalization of Cu3BTC2@IL composites with Pd(II) for catalytic applications
(2017-10-29)
Metal-organic frameworks could be excellent supports for active catalytic species in order to obtain heterogeneous and reusable catalysts, easily removable from the reaction media.[1,2] Additionally, the presence of ...
Ionic liquids in the control of the poly(vinylidene fluoride-co- hexafluoropropylene) membranes morphology [Poster]
(2017-10-27)
The development of polymer membranes with tailored micro-morphology and wettability are a demand in the areas of filtration, sensors or tissue engineering, among others. Poly(vinylidene fluoride-co-hexafluoropropylene) ...
Materiales de tipo MOF orientados a la adsorción de contaminantes y catálisis heterogénea. Nuevas perspectivas.
(2017-11-22)
Nuestro grupo de investigación cuenta con una amplia experiencia en la síntesis y
caracterización de materiales multifuncionales basados en redes de coordinación porosas de
tipo MOF (metal-organic framework). La estrategia ...
M(C6H16N3)2(VO3)4 as heterogeneous catalysts. Study of three new hybrid vanadates of cobalt(II), nickel(II) and copper(II) with 1-(2-aminoethyl)piperazonium.
(Royal Society of Chemistry, 2011-10-14)
Three new hybrid vanadates have been synthesized under hydrothermal conditions with the formula M(C6H16N3)2(VO3)4, where M= Co(II), Ni(II) and Cu(II). The structural analyses show that the phases are isostructural and ...
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
(Elsevier, 2011-08-03)
The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ...
Metalloporphyrin-based MOFs: new strategies for catalyst immobilization
(2016-04-25)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
(MDPI (Multidisciplinary Digital Publishing Institute) Basel, Switzerland, 2015-04-15)
Synthetic metalloporphyrin complexes are often used as analogues of natural
systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ...
Self-assembly of metalloporphyrins: first TPP-bipy coordination polymer with CoII (TPP=meso-tetraphenylporphyrin and bipy=4,4´-bipyridine)
(2015-10-23)
Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ...