Show simple item record

Luminescence and Magnetic Properties of Two Three -Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4 '-Dicarboxylic Linker

dc.contributor.authorFernández, Belén
dc.contributor.authorOyarzabal Epelde, Itziar
dc.contributor.authorSeco Botana, José Manuel ORCID
dc.contributor.authorSan Sebastián Larzabal, Eider ORCID
dc.contributor.authorFairen-Jiménez, David
dc.contributor.authorGómez-Ruiz, Santiago ORCID
dc.contributor.authorSalinas-Castillo, Alfonso
dc.contributor.authorCalahorro, Antonio J.
dc.contributor.authorRodríguez-Diéguez, Antonio
dc.date.accessioned2016-05-12T13:30:46Z
dc.date.available2016-05-12T13:30:46Z
dc.date.issued2016-02
dc.identifier.citationPolymers 8(2) : (2016) // Article ID 39es
dc.identifier.issn2073-4360
dc.identifier.urihttp://hdl.handle.net/10810/18241
dc.description.abstractWe report the in situ formation of two novel metal-organic frameworks based on terbium and dysprosium ions using azobenzene-4,4-dicarboxylic acid (H(2)abd) as ligand, synthesized by soft hydrothermal routes. Both materials show isostructural three-dimensional networks with channels along a axis and display intense photoluminescence properties in the solid state at room temperature. Textural properties of the metal-organic frameworks (MOFs) have been fully characterized although no appreciable porosity was obtained. Magnetic properties of these materials were studied, highlighting the dysprosium material displays slightly frequency-dependent out of phase signals when measured under zero external field and under an applied field of 1000 Oe.es
dc.description.sponsorshipThis work was supported by the MEC of Spain (Project CTQ2011-24478) and the Junta de Andalucia (FQM-1484 and FQM-195). David Fairen-Jimenez thanks the Royal Society for a University Research Fellowship. Itziar Oyarzabal is grateful to the Departamento de Educacion, Universidades e Investigacion del Gobierno Vasco for a predoctoral fellowship. The authors thank for technical and human support provided by SG Iker Gipuzkoa of UPV/EHU.es
dc.language.isoenges
dc.publisherMDPIes
dc.rightsinfo:eu-repo/semantics/openAccesses
dc.subjectmetal-organic frameworkes
dc.subjectdysprosiumes
dc.subjectterbiumes
dc.subjectmagnetismes
dc.subjectluminescencees
dc.subjectcrystal-structureses
dc.subjectfluorescencees
dc.subjectcomplexeses
dc.subjectdesignes
dc.titleLuminescence and Magnetic Properties of Two Three -Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4 '-Dicarboxylic Linkeres
dc.typeinfo:eu-repo/semantics/articlees
dc.rights.holder© 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons by Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).es
dc.relation.publisherversionhttp://www.mdpi.com/2073-4360/8/2/39es
dc.identifier.doi10.3390/polym8020039
dc.departamentoesQuímica aplicadaes_ES
dc.departamentoeuKimika aplikatuaes_ES
dc.subject.categoriaCHEMISTRY, MATERIALS


Files in this item

Thumbnail
Name:
polymers-08-00039-1.pdf
Size:
2.661Mb
Format:
PDF
View/Open

This item appears in the following Collection(s)

Show simple item record