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Tuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Molecules

dc.contributor.authorSola Llano, Rebeca
dc.contributor.authorMartínez Martínez, Virginia ORCID
dc.contributor.authorFurukawa, Shuhei
dc.contributor.authorTakashima, Yohei
dc.contributor.authorLópez Arbeloa, Iñigo María
dc.date.accessioned2019-03-12T13:50:35Z
dc.date.available2019-03-12T13:50:35Z
dc.date.issued2018-02
dc.identifier.citationPolymers 10(2) : (2018) // Article ID 188es_ES
dc.identifier.issn2073-4360
dc.identifier.urihttp://hdl.handle.net/10810/31985
dc.description.abstractTaking advantage of the outstanding properties of a naphthalenediimide-based entangled porous coordination polymer, a simple strategy for the achievement of white light emission is herein presented. The dynamic structural transformation of the [Zn-2(bdc)(2)(dpNDI)](n) metal-organic framework enhances the interactions with aryl-guests giving rise to different luminescence colors upon UV (ultraviolet) illumination. Thus, through the rational selection of those small aromatic guest molecules with different electron donor substituents at the appropriate proportion, the emission color was tuned by mixture ratio of guest molecules and even white light emission was achieved. Furthermore, domains in large crystals with a complementary response to linearly polarized light were noticed.es_ES
dc.description.sponsorshipThis work was funded by the Spanish MINECO (MAT2017-83856-C3-3-P) and from Gobierno Vasco (IT912-16). iCeMS is supported by the World Premier International Research Initiative (WPI), MEXT, Japan.es_ES
dc.language.isoenges_ES
dc.publisherMDPIes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/MAT2017-83856-C3-3-Pes_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.subjectentangled MOF (metal organic framework)es_ES
dc.subjectaryl guestses_ES
dc.subjectcharge transferes_ES
dc.subjectwhite light emissiones_ES
dc.subjectCIE (Comission Internationale de l'Eclairage) coordinateses_ES
dc.subjectUV illuminationes_ES
dc.subjectwhite light emissiones_ES
dc.subjectcharge-transferes_ES
dc.titleTuning Light Emission towards White Light from a Naphthalenediimide-Based Entangled Metal-Organic Framework by Mixing Aromatic Guest Moleculeses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holderThis is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).es_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://www.mdpi.com/2073-4360/10/2/188es_ES
dc.identifier.doi10.3390/polym10020188
dc.departamentoesQuímica físicaes_ES
dc.departamentoeuKimika fisikoaes_ES


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This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).
Except where otherwise noted, this item's license is described as This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited (CC BY 4.0).