| dc.contributor.author | Olaizola Aizpuru, Olatz | |
| dc.contributor.author | Iriarte Arrieta, Igor | |
| dc.contributor.author | Zanella, Giovanna | |
| dc.contributor.author | Gómez Bengoa, Enrique | |
| dc.contributor.author | Gamboa Landa, José Ignacio | |
| dc.contributor.author | Oyarbide Garmendia, Juan Miguel | |
| dc.contributor.author | Palomo Nicolau, Claudio | |
| dc.date.accessioned | 2021-06-29T18:06:21Z | |
| dc.date.available | 2021-06-29T18:06:21Z | |
| dc.date.issued | 2019-07-31 | |
| dc.identifier.citation | Angewandte Chemie International Edition 58(40) : 14250-14254 (2019) | es_ES |
| dc.identifier.issn | 1433-7851 | |
| dc.identifier.uri | http://hdl.handle.net/10810/52087 | |
| dc.description.abstract | Acatalyst-driven one-pot reaction sequence is
developed for the enantio- and diastereoselective synthesis of
tetrasubstituted cyclohexenes from simple unsaturated ketones
or thioesters.The method involves atertiary amine/squara-
mide-catalyzed a-selective addition of transiently generated
trienolates to nitroolefins,subsequent base-catalyzed double
bond isomerization, and an intramolecular (vinylogous) 1,6-
addition reaction, arare key carbocyclization step that
proceeded with essentially perfect stereocontrol | es_ES |
| dc.description.sponsorship | Support has been provided by the University of the Basque Country UPV/EHU (UFI QOSYC 11/22), the Basque Government (GV grant No IT-1236-19), and the Ministerio de Economía y Competitividad (MEC Grant CTQ2016-78487-C2), Spain. I.I. and O.O. thank GV for a fellowship. G.Z. and E.G.-B thank the European Funding Horizon 2020-MSCA (ITN-EJD CATMEC 14/06-721223). | es_ES |
| dc.language.iso | eng | es_ES |
| dc.publisher | Wiley-VCH | es_ES |
| dc.relation | info:eu-repo/grantAgreement/EC/H2020/721223 | es_ES |
| dc.relation | info:eu-repo/grantAgreement/MINECO/CTQ2016-78487-C2 | es_ES |
| dc.rights | info:eu-repo/semantics/openAccess | es_ES |
| dc.title | Brønsted Base Catalyzed One-Pot Synthesis od Stereodefined Six-Member Carbocycles Featuring Transient Trienolates and a Key Intramolecular 1,6-Addition | es_ES |
| dc.type | info:eu-repo/semantics/article | es_ES |
| dc.rights.holder | © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | es_ES |
| dc.relation.publisherversion | https://onlinelibrary.wiley.com/doi/full/10.1002/anie.201908693 | es_ES |
| dc.identifier.doi | doi.org/10.1002/anie.201908693 | |
| dc.identifier.doi | 10.1002/anie.201908693 | |
| dc.contributor.funder | European Commission | |
| dc.departamentoes | Química orgánica I | es_ES |
| dc.departamentoeu | Kimika organikoa I | es_ES |
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