Effect of crystallization of the polyhedral oligomeric silsesquioxane block on self-assembly in hybrid organic-inorganic block copolymers with salt
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Date
2021-03-01Author
Sethi, Gurmukh K.
Chakraborty, Saheli
Zhu, Chenhui
Schaible, Eric
Villaluenga Arranz, Irune
Balsara, Nitash P.
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Giant 6 : (2021) // Article ID 100055
Abstract
[EN] We present a DSC and X-ray scattering study investigating the effect of polyhedral oligomeric silsesquioxane (POSS) block crystallinity on the self-assembly of a poly(acryloisobutyl polyhedral oligomeric silsesquioxane)- b -poly(ethylene oxide)- b -poly(acryloisobutyl polyhedral oligomeric silsesquioxane) (POSS-PEO-POSS) triblock copolymer and poly(ethylene oxide)- b - poly(acryloisobutyl polyhedral oligomeric silsesquioxane) (PEO-POSS) diblock copolymers mixed with lithium bis(trifluoromethanesulfonyl)imide salt. The POSS block in all copolymer/salt mixture organizes into a rhombohedral crystal, similar to that of the POSS homopolymer. Semicrystalline polymer/salt mixtures favor morphologies with flat interfaces ( i.e ., lamellae) despite the asymmetric nature of the copolymers; PEO/salt volume fractions range from 0 to 0.85. Coexisting lamellae and hexagonally packed cylinders as well as coexisting lamellae with different domain spacings are seen in many copolymer/salt mixtures wherein the POSS block is amorphous. Morphological phase transitions in these systems are seen in the vicinity of the POSS crystallization temperature.