Show simple item record

Multifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenols

dc.contributor.authorLópez de Lacalle Zabaleta, Jon
dc.contributor.authorGallastegui, Antonela
dc.contributor.authorOlmedo Martínez, Jorge L.
dc.contributor.authorMoya, Melissa
dc.contributor.authorLópez Larrea, Naroa
dc.contributor.authorPicchio, Matías L.
dc.contributor.authorMecerreyes Molero, David
dc.date.accessioned2023-03-14T18:16:06Z
dc.date.available2023-03-14T18:16:06Z
dc.date.issued2023-01
dc.identifier.citationACS Macro Letters 12(2) : 125-132 (2023)es_ES
dc.identifier.issn2161-1653
dc.identifier.urihttp://hdl.handle.net/10810/60354
dc.description.abstractHerein we report a novel family of deep eutectic monomers and the corresponding polymers, made of (meth)acrylic ammonium salts and a series of biobased polyphenols bearing catechol or pyrogallol motifs. Phenolic chemistry allows modulating molecular interactions by tuning the ionic polymer properties from soft adhesive to tough materials. For instance, pyrogallol and hydrocaffeic acid-derived ionic polymers showed outstanding adhesiveness (>1 MPa), while tannic acid/gallic acid polymers with dense hydrogen bond distribution afforded ultratough elastomers (stretchability ≈1000% and strength ≈3 MPa). Additionally, phenolic polymeric deep eutectic solvents (polyDES) featured metal complexation ability, antibacterial properties, and fast processability by digital light 3D printing.es_ES
dc.description.sponsorshipThis work was supported by Marie Sklodowska-Curie Research and Innovation Staff Exchanges (RISE) under grant agreement no. 823989 “IONBIKE”. The financial support from CONICET and ANPCyT (PICT 2018-01032) (Argentina) is also gratefully acknowledged.es_ES
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relationinfo:eu-repo/grantAgreement/EC/H2020/823989es_ES
dc.rightsinfo:eu-repo/semantics/openAccesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/es/*
dc.titleMultifunctional Ionic Polymers from Deep Eutectic Monomers Based on Polyphenolses_ES
dc.typeinfo:eu-repo/semantics/articlees_ES
dc.rights.holder© 2023 The Authors. Published by American Chemical Society. Attribution 4.0 International (CC BY 4.0)es_ES
dc.rights.holderAtribución 3.0 España*
dc.relation.publisherversionhttps://pubs.acs.org/doi/10.1021/acsmacrolett.2c00657es_ES
dc.identifier.doi10.1021/acsmacrolett.2c00657
dc.contributor.funderEuropean Commission
dc.departamentoesQuímica aplicadaes_ES
dc.departamentoeuKimika aplikatuaes_ES


Files in this item

Thumbnail
Name:
acsmacrolett.2c00657.pdf
Size:
6.074Mb
Format:
PDF
Description:
Artículo
View/Open
Thumbnail
Name:
license_rdf
Size:
914bytes
Format:
application/rdf+xml
View/Open

This item appears in the following Collection(s)

Show simple item record

© 2023 The Authors. Published by American Chemical Society. Attribution 4.0 International (CC BY 4.0)
Except where otherwise noted, this item's license is described as © 2023 The Authors. Published by American Chemical Society. Attribution 4.0 International (CC BY 4.0)