Gas reactions under intrapore condensation regime within tailored metal–organic framework catalysts
dc.contributor.author | Agirrezabal Telleria, Iker | |
dc.contributor.author | Luz, Ignacio | |
dc.contributor.author | Ortuño, Manuel A. | |
dc.contributor.author | Oregui Bengoechea, Mikel | |
dc.contributor.author | Gandarias Goikoetxea, Iñaki | |
dc.contributor.author | López, Núria | |
dc.contributor.author | Lail, Marty A. | |
dc.contributor.author | Soukri, Mustapha | |
dc.date.accessioned | 2024-02-08T09:43:09Z | |
dc.date.available | 2024-02-08T09:43:09Z | |
dc.date.issued | 2019-05-06 | |
dc.identifier.citation | Nature Communications 10 : (2019) // Article ID 2076 | es_ES |
dc.identifier.issn | 2041-1723 | |
dc.identifier.uri | http://hdl.handle.net/10810/65107 | |
dc.description.abstract | [EN] roduction of 1-butene, a major monomer in polymer industry, is dominated by homogeneous protocols via ethylene dimerization. Homogeneous catalysts can achieve high selectivity but require large amounts of activators and solvents, and exhibit poor recyclability; in turn, heterogeneous systems are robust but lack selectivity. Here we show how the precise engineering of metal–organic frameworks (MOFs) holds promise for a sustainable process. The key to the (Ru)HKUST-1 MOF activity is the intrapore reactant condensation that enhances ethylene dimerization with high selectivity (> 99% 1-butene) and high stability (> 120 h) in the absence of activators and solvents. According to spectroscopy, kinetics, and modeling, the engineering of defective nodes via controlled thermal approaches rules the activity, while intrapore ethylene condensation accounts for selectivity and stability. The combination of well-defined actives sites with the concentration effect arising from condensation regimes paves the way toward the development of robust MOF catalysts for diverse gas-phase reactions. | es_ES |
dc.description.sponsorship | This work was financially supported by the research fund from Basque Government (IT993–16) and RTI international funds. M.A.O. and N.L. acknowledge BSC-RES for generous computer resources (RES-QCM-2018–2–0020). M.A.O. acknowledges the “Juan de la Cierva–Incorporación” programme from MINECO (IJCI-2016–29762) and the “Beatriu de Pinós” programme from AGAUR (2017-BP-00039). | es_ES |
dc.language.iso | eng | es_ES |
dc.publisher | Springer Nature | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/JCI-2016–29762 | |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by/4.0/ | * |
dc.subject | MOF | es_ES |
dc.subject | intrapore condensation regime | es_ES |
dc.subject | gas reactions | es_ES |
dc.title | Gas reactions under intrapore condensation regime within tailored metal–organic framework catalysts | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © The Author(s) 2019. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/. | es_ES |
dc.relation.publisherversion | https://www.nature.com/articles/s41467-019-10013-6 | es_ES |
dc.identifier.doi | /10.1038/s41467-019-10013-6 | |
dc.departamentoes | Ingeniería química y del medio ambiente | es_ES |
dc.departamentoeu | Ingeniaritza kimikoa eta ingurumenaren ingeniaritza | es_ES |
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Except where otherwise noted, this item's license is described as © The Author(s) 2019. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.