Controlled placement of polystyrene-grafted CdSe nanoparticles in self-assembled block copolymers
Fecha
2013Autor
Etxeberria Altuna, Haritz
Zalakain, Iñaki
Fernández Salvador, Raquel
Kortaberria Altzerreka, Galder
Mondragón Egaña, Iñaki Bixintxo
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Colloid and Polymer Science 291 : 633-640 (2013)
Resumen
Surface functionalization of semiconductor CdSe nanoparticles has been achieved with polystyrene (PS) brushes by “grafting from” technique for further addition to a polystyrene-b-polybutadiene-b-polystyrene (SBS) block copolymer in order to obtain self-assembled composites. For modification of nanoparticle surface 3-glycidoxypropyltrimethoxysilane (GPS) was used at first for the later attachment of the 4,4´-azobis(4-cyanopentanoic acid) (ACP) azo initiator. Fourier transform infrared spectroscopy (FTIR) confirmed the presence of GPS and PS on the surface of nanoparticles. Atomic force microscopy (AFM) was used for morphological characterization of SBS/CdSe nanocomposites. Modification of nanoparticles with PS brushes by radical polymerization improved their affinity with PS block and the dispersion of nanoparticles avoiding agglomeration. CdSe nanoparticle size was measured to be around 2 nm by the use of X-ray diffraction (XRD) and UV-vis techniques. Optical properties were characterized using fluorescence measurements.