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Improving the barrier character of poly(caprolactone): transport properties and free volume of immiscible blends
dc.contributor.author | Sangroniz Agudo, Ainara | |
dc.contributor.author | Sangroniz Agudo, Leire | |
dc.contributor.author | González Vives, Alba | |
dc.contributor.author | Santamaría Ibarburu, Pedro Antonio | |
dc.contributor.author | del Río, Javier | |
dc.contributor.author | Etxeberria Lizarraga, Agustín | |
dc.date.accessioned | 2024-02-08T11:15:22Z | |
dc.date.available | 2024-02-08T11:15:22Z | |
dc.date.issued | 2019-03-11 | |
dc.identifier.citation | European Polymer Journal 115 : 76-85 (2019) | es_ES |
dc.identifier.issn | 0014-3057 | |
dc.identifier.issn | 1873-1945 | |
dc.identifier.uri | http://hdl.handle.net/10810/65500 | |
dc.description.abstract | Miscible and thermally stable blends of biodegradable poly(butylene adipate-co-terephthalate) (PBAT) with poly(hydroxy ether of bisphenol A) (PH) are investigated to obtain membranes for packaging applications. Previously the miscibility and adequate degradability of these blends was proven, therefore this system is a good candidate for packaging applications. The crystallinity degree and the free volume, both of crucial importance in transport properties, are analysed as a function of blend composition. The transport properties to different gases and vapours are greatly reduced with the addition of PH. The blends show high elongational viscosity values, which allows expecting good film processability. Overall, this work sheds light on the factors involved in the reduction of permeability which would allow to broaden this strategy to other promising biodegradable materials. | es_ES |
dc.description.sponsorship | The authors are grateful to the financial support from the Basque Government (GIC IT-618-13 and GIC IT-586-13) and Spanish Ministry of Innovation and Competitiveness MINECO (MAT-2016-78527-P). A. Sangroniz and L. Sangroniz thank the Basque Government and Spanish Ministry (FPU), respectively, for their PhD grants. | |
dc.language.iso | eng | es_ES |
dc.publisher | Elsevier | es_ES |
dc.relation | info:eu-repo/grantAgreement/MINECO/MAT-2016-78527-P | |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | * |
dc.subject | biodegradable polymer | es_ES |
dc.subject | free volume | |
dc.subject | permeability | |
dc.subject | packaging | |
dc.title | Improving the barrier character of poly(caprolactone): transport properties and free volume of immiscible blends | es_ES |
dc.type | info:eu-repo/semantics/article | es_ES |
dc.rights.holder | © 2019 Elsevier under CC BY-NC-ND license | * |
dc.relation.publisherversion | https://www.sciencedirect.com/science/article/pii/S0014305718324248 | |
dc.identifier.doi | /10.1016/j.eurpolymj.2019.03.026 | |
dc.departamentoes | Ciencia y tecnología de polímeros | es_ES |
dc.departamentoeu | Polimeroen zientzia eta teknologia | es_ES |