An overview of the applications of chiral phosphoric acid organocatalysts in enantioselective additions to C=O and C=N bonds

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Ikusi/Ireki
Data
2022-09-07
Egilea
Del Corte Solaguren-Beascoa, Xabier
Martínez de Marigorta Izaga, Edorta ORCID
Palacios Gambra, Francisco Javier ORCID
Vicario Hernando, Javier ORCID
Maestro Burzaco, Aitor
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Organic Chemistry Frontiers 9(22) : 6331-6399 (2022)
URI
http://hdl.handle.net/10810/70065
Laburpena
Chiral phosphoric acids (CPAs) have been used as efficient organocatalysts since the first examples were reported 18 years ago by Akiyama and Terada. Although they were originally developed for enantioselective additions to imines, a wide reaction scope has been demonstrated using this type of catalyst. In this review, the known applications of CPA for enantioselective additions to C=O and C=N bonds are covered.
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