Browsing by Author "Mendicute Fierro, Claudio"
Now showing items 1-9 of 9
-
A Lamellar Zn-Based Coordination Polymer Showing Increasing Photoluminescence upon Dehydration
Pajuelo Corral, Oier; García Martínez, José Angel; Castillo García, Oscar ; Luque Arrebola, Antonio ; Mendicute Fierro, Claudio; Rodríguez Diéguez, Antonio; Cepeda Ruiz, Javier (MDPI, 2023-07-25)The present study reports on a 2D lamellar coordination polymer (CP) of {[Zn(µ3-pmdc)(H2O)]·H2O}n formula (pmdc = pyrimidine-4,6-dicarboxylate). This CP is synthesized under an appropriate acid-base reaction between the ... -
Desarrollo de nanopartículas de sílice multifuncionalizadas como potenciales agentes terapéuticos para infecciones bacterianas y cáncer.
Ugalde Arbizu, Maider (2023-01-13)En la presente Tesis Doctoral se han desarrollado nuevos agentes terapéuticos y/o de diagnóstico eficaces y selectivos contra el cáncer de mama ductal invasivo triple negativo y/o las infecciones bacterianas en heridas y ... -
Efficient Homogeneous Hydridoirida-β-Diketone-Catalyzed Methanolysis of Ammonia-Borane for Hydrogen Release in Air. Mechanistic Insights
Bustos Rosas, Itxaso; Freixa Fernández, Zoraida; Pazos Pérez, Ariadna; Mendicute Fierro, Claudio; Garralda Hualde, María Angeles (Wiley, 2021-08-20)The hydridoirida-beta-diketone [(IrH{(PPh2(o-C6H4CO))(2)H})(2)(mu-Cl)][BF4] (2) has been used as a homogeneous catalyst for the methanolysis of ammonia-borane to release up to 3 equivalents of hydrogen in the presence of ... -
Formation of Irida-β-ketoimines and PCNamine-Ir(III) Complexes by Reacting Irida-β-diketones with Aliphatic Diamines: Catalytic Activity in Hydrogen Release by Methanolysis of H3N–BH3
Bustos Rosas, Itxaso; Seco Botana, José Manuel ; Rodríguez Diéguez, Antonio; Garralda Hualde, María Angeles ; Mendicute Fierro, Claudio (ACS, 2022-12-01)Aliphatic diamines [(H2N(CH2)nNHR) (a–d) n = 2: R = H (a), R = CH3 (b), R = C2H5 (c), n = 3, R = H (d) or rac-2-(aminomethyl)piperidine (e)] react with [IrH(Cl){(PPh2(o-C6H4CO))2H}] in THF to afford ketoimine complexes ... -
Interes biologikoa daukaten, beraien artean zitratoa, koordinazio konposatuen sintesia eta karakterizazioa
Ugalde Arbizu, Maider (2016-11-30)[EU]Lan honen helburu nagusia, interes biologikoa daukaten koordinazio polimeroen sintesia eta karakterizazioa da. Horretarako, helburu biologikoak dauzkaten ligandoak zein metal biobateragarriak erabili dira. Hori burutzeko, ... -
Irida-ß-diketones and Iridapyrazoles: reactivity and catalytic activity in amine-borane solvolysis for hydrogen release
Bustos Rosas, Itxaso (2021-05-28)Se han sintetizado nuevos complejos derivados de irida-ß-dicetonas con ligandos amino-éter y diaminas alquílicas. Los primeros, los derivados con un ligando amino-éter, han sido probados como catalizadores para la obtención ... -
Irida-β-ketoimines derived from Hydrazines to Afford Metallapyrazoles or N-N Bond Cleavage: A Missing Metallacycle Disclosed by a Theoretical and Experimental Study
Zumeta Subijana, Itziar; Mendicute Fierro, Claudio; Bustos Rosas, Itxaso; Huertos Mansilla, Miguel Angel; Rodríguez Diéguez, Antonio; Seco Botana, José Manuel ; San Sebastián Larzabal, Eider ; Garralda Hualde, María Angeles (ACS, 2016)Unprecedented metallapyrazoles [IrH2{Ph2P(o-C6H4)CNNHC(o-C6H4)PPh2}] (3) and [IrHCl{Ph2P(o-C6H4)CNNHC(o-C6H4)PPh2}] (4) were obtained by the reaction of the irida-β-ketoimine [IrHCl{(PPh2(o-C6H4CO))(PPh2(o-C6H4CNNH2))H}] ... -
Iridium(III)-based photoluminescent sensors for Ba2+ tagging: toward background-free Ba2+ sensing
Aranburu Leiva, Ane Izaskun (2023-03-31)En la presente tesis doctoral se han desarrollado complejos de iridio(III) para su aplicación como sensores fotoluminiscentes de Ba2+, dentro del contexto de la colaboración NEXT para Ba2+-tagging Las estructuras son ... -
Structure of a dinickel(II)-dithiolate bridged macrocyclic complex synthesised via a novel solvent-assisted disulfide cleavage reaction
Mendicute Fierro, Claudio; Smith, Paul D.; Light, Mark E. (Elsevier, 2023-01)The reaction of 2,6-diformyl-4-methylphenyl disulfide with [Ni(tn)3]Cl2 (tn = 1,3-diaminopropane), in methanol and in the presence of NaBPh4 resulted in the isolation of [Ni2(L1)](DMF)2(BPh4)2 (I), (L1 = 15,95-dimethyl-3 ...