Examinar por departamento (eus.) "Kimika Organikoa eta Ez-Organikoa"
Now showing items 61-80 of 131
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Linear Polyethyleneimine-Based and Metal Organic Frameworks (DUT-67) Composite Hydrogels as Efficient Sorbents for the Removal of Methyl Orange, Copper Ions, and Penicillin V
(MDPI, 2023-11-16)This research explores the integration of DUT-67 metal organic frameworks into polyethyleneimine-based hydrogels to assemble a composite system with enough mechanical strength, pore structure and chemical affinity to work ... -
Lithium Iron Phosphate/Carbon (LFP/C) Composite Using Nanocellulose as a Reducing Agent and Carbon Source
(MDPI, 2023-06-09)Lithium iron phosphate (LiFePO4, LFP) is the most promising cathode material for use in safe electric vehicles (EVs), due to its long cycle stability, low cost, and low toxicity, but it suffers from low conductivity and ... -
Making Room for Silicon: Including SiOx in a Graphite-Based Anode Formulation and Harmonization in 1 Ah Cells
(MDPI, 2024-03-28)Transitioning to more ambitious electrode formulations facilitates developing high-energy density cells, potentially fulfilling the demands of electric car manufacturers. In this context, the partial replacement of the ... -
MATEO: intermolecular α-amidoalkylation theoretical enantioselectivity optimization. Online tool for selection and design of chiral catalysts and products
(BMC, 2024-01-23)The enantioselective Brønsted acid-catalyzed α-amidoalkylation reaction is a useful procedure is for the production of new drugs and natural products. In this context, Chiral Phosphoric Acid (CPA) catalysts are versatile ... -
Merging porosity with magnetism and fluorescence in metal-organic materials for sensing purposes
(2022-07-21)El trabajo de tesis tiene por objetivo generar materiales donde combinemos porosidad con otra propiedad fácilmente medible para generar sensores químicos. En este sentido los materiales con porosidad elevada son ideales ... -
Metal-Catalyzed Cascade Reactions between Alkynoic Acids and Dinucleophiles: A Review
(MDPI, 2023-02-28)Cascade reactions provide a straightforward access to many valuable compounds and reduce considerably the number of steps of a synthetic sequence. Among the domino and multicomponent processes that involve alkynes, the ... -
Metal-organic aerogels based on titanium(IV) for visible-light conducted CO2 photoreduction to alcohols
(Elsevier, 2022-12)Metal-organic frameworks (MOFs) imply an appealing source of photocatalysts as they combine porosity with tailorable electronic properties and surface chemistry. Herein, we report a series of unprecedented metal-organic ... -
Metal-organic porous materials for carbon dioxide valorization, water adsorption and photocatalitic hydrogen production
(2023-03-29)Esta tesis doctoral se fundamenta en el desarrollo de materiales metal-orgánicos porosos como son las redes metal-orgánicas (metal-organic frameworks, MOFs), los geles metal-orgánicos (metal-organic gels, MOGs) y los ... -
Microwave-assisted Palladium catalysed C-H acylation with aldehydes. Synthesis and diversification of 3-acylthiophenes
(Royal Society of Chemistry, 2021-12-22)The use of MW allows the efficient palladium(II)-catalysed C-3 acylation of thiophenes with aldehydes via C(sp2)-H activation for the synthesis of (cyclo)alkyl/aryl thienyl ketones (43 examples). Compared to standard thermal ... -
MLb-LDLr: A Machine Learning Model for Predicting the Pathogenicity of LDLr Missense Variants
(Elsevier, 2021-11)Untreated familial hypercholesterolemia (FH) leads to atherosclerosis and early cardiovascular disease. Mutations in the low-density lipoprotein receptor (LDLr) gene constitute the major cause of FH, and the high number ... -
Molecular Recognition of Glycan-Bearing Glycomacromolecules Presented at Membrane Surfaces by Lectins: An NMR View
(American Chemical Society, 2023-05)Lectin–glycan interactions are at the heart of a multitude of biological events. Glycans are usually presented in a multivalent manner on the cell surface as part of the so-called glycocalyx, where they interact with other ... -
Multicomponent synthesis of γ-lactam derivatives and applications as anticancer agents
(2022-10-06)Cancer, the name given to a collection of neoplastic diseases, is the second most important global cause of death. For ages, the treatment of these diseases has been a highly complex process and, although several innovative ... -
Multifunctional Lanthanide-Based Metal-Organic Frameworks Derived from 3-Amino-4-hydroxybenzoate: Single-Molecule Magnet Behavior, Luminescent Properties for Thermometry, and CO2 Adsorptive Capacity
(American Chemical Society, 2022-08)Herein, we describe and study a new family of isostructural multifunctional metal-organic frameworks (MOFs) with the formula {[Ln(5)L(6)(OH)(3)(DMF)(3)]center dot 5H(2)O} n (where (H2L) is 3-amino-4-hydroxybenzoic acid ... -
Nanostructured Manganese Dioxide for Hybrid Supercapacitor Electrodes
(MDPI, 2022-11-30)Hybrid supercapacitors, as emerging energy storage devices, have gained much attention in recent years due to their high energy density, fast charge/discharge and long cyclabilities. Among the wide range of systems covered ... -
New Glucosamine-Based TLR4 Agonists: Design, Synthesis, Mechanism of Action, and In Vivo Activity as Vaccine Adjuvants
(American Chemical Society, 2023-02)We disclose here a panel of small-molecule TLR4 agonists (the FP20 series) whose structure is derived from previously developed TLR4 ligands (FP18 series). The new molecules have increased chemical stability and a shorter, ... -
New palladium catalysts for cross-coupling, cycloisomerization, cascade and multicomponent reactions
(2021-06-18)Este trabajo de investigación se centra en la síntesis de tres nuevos complejos pincer de paladio, así como en el estudio de su actividad catalítica en la reacción de acoplamiento cruzado de Suzuki-Miyaura y la cicloisomerización ... -
New synthetic procedures based on copper-catalyzed cycloisomerization of alkynoic acids
(2023-03-10)El presente trabajo de investigación recoge el estudio y desarrollo de nuevas metodologías sintéticas basadas en procesos en cascada a partir de la cicloisomerización de ácidos alquinoicos catalizada por cobre. Además de ... -
NIFPTML: Network invariant, information fusion, perturbation theory, machine learning study of dual antibacterial drugs-nanoparticles (DADNP) systems-metabolic networks interaction.
(2022-07-11)La combinación de enfoques computacionales clásicos con técnicas de aprendizaje automático (MLT) está ganando adeptos en el mundo académico y en la industria. Las MLT se utilizan en procesos de quimioinformática para ... -
NMR and molecular recognition: The interaction of human galectin-4 with the histo blood group antigens and with pathogen-associated molecules
(2022-10-05)Glycans are essential molecules that are ubiquitously found in every living cell. The interaction betweengalect in 4, a human sugar binding protein, with the histo blood group antigens has been studied by NuclearMagnetic ... -
NMR and molecular recognition: The interaction of human galectin-8 and DC-SIGN with natural glycans and glycomimetics.
(2023-03-22)Glycans are everywhere in Nature, where they play a plethora of functions in every domain of life. The recognition of glycans by lectins is at the heart of a myriad of biological proceses, including host-pathogen interactions, ...