Browsing by Author "Almenara Pérez, Naroa"
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Activación de enlaces E-H (E= C, P, Si) por metales de transición. Influencia en catálisis homogenea.
Almenara Pérez, Naroa (2020-10-23)Se han sintetizado nuevos complejos de rodio(III) partiendo de dímeros o monómeros de rodio(I), con diversas fosfinas u óxidos de fosfina (SPO) y con una variedad de ligandos. La reacciones de síntesis se llevan a cabo ... -
Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes
Almenara Pérez, Naroa; Garralda Hualde, María Angeles ; López de Pariza Sanz, Xabier; Matxain Beraza, Jon Mattin ; Freixa Fernández, Zoraida; Huertos Mansilla, Miguel Angel (Wiley, 2022-09-05)[EN] An unprecedented quantum tunneling effect has been observed in catalytic Si-H bond activations at room temperature. The cationic hydrido-silyl-iridium(III) complex, {Ir[SiMe(o-C6H4SMe)(2)](H)(PPh3)(THF)}[BAr4F], has ... -
Lignin–Chitosan Gel Polymer Electrolytes for Stable Zn Electrodeposition
Almenara Pérez, Naroa; Gueret, Robin; Huertas Alonso, Alberto J.; Veettil, Unnimaya Thalakkale; Sipponen, Mika H.; Lizundia Fernández, Erlantz (American Chemical Society, 2023-01)Electrochemical energy storage technologies offer means to transition toward a decarbonized society and carbon neutrality by 2050. Compared to conventional lithium-ion batteries, aqueous zinc-ion chemistries do not require ... -
Oxidative Addition of Secondary Phosphine Oxides through Rh(I) Center: Hydrido-Phosphinito-Rh(III) Complexes and their Catalytic Activity in Hydrophosphinylation of Alkynes
Almenara Pérez, Naroa; Barquín Muga, María Montserrat; Huertos Mansilla, Miguel Angel; Garralda Hualde, María Angeles (Wiley, 2021-12-21)[EN]The reaction of [Rh(mu-Cl)(cod)](2) with diimines, differing in their steric and electronic properties, and with diphenylphosphine oxide leads to the oxidative addition products, hydrido-phosphinito-Rh(III) complexes ...