Browsing by Author "García Moreno, Inmaculada"
Now showing items 1-10 of 10
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4,4′-Dicyano- versus 4,4′-Difluoro-BODIPYs in Chemoselective Postfunctionalization Reactions: Synthetic Advantages and Applications
Ventura, Juan; Uriel, Clara; Gómez López, Ana María; Avellanal Zaballa, Edurne; Bañuelos Prieto, Jorge ; Rebollar, Esther ; García Moreno, Inmaculada; López Pérez, José Cristóbal (American Chemical Society, 2023-04)The presence of F or CN substituents at boron in BODIPYs causes a dramatic effect on their reactivity, which allows their chemoselective postfunctionalization. Thus, whereas 1,3,5,7-tetramethyl B(CN)2-BODIPYs displayed ... -
A Computational-Experimental Approach to Unravel the Excited State Landscape in Heavy-Atom Free BODIPY-Related Dyes
Rebollar, Esther ; Bañuelos Prieto, Jorge ; de la Moya, Santiago; Eng, Julien ; Penfold, Thomas ; García Moreno, Inmaculada (MDPI, 2022)We performed a time-gated laser-spectroscopy study in a set of heavy-atom free single BODIPY fluorophores, supported by accurate, excited-state computational simulations of the key low-lying excited states in these ... -
A concise route to water-soluble 2,6-disubstituted BODIPY-carbohydrate fluorophores by direct Ferrier-type C‑Glycosylation
Gómez López, Ana María; Uriel, Clara; Oliden Sánchez, Ainhoa; Bañuelos Prieto, Jorge ; García Moreno, Inmaculada; López Pérez, José Cristóbal (American Chemical Society, 2021-06-22)[EN] Novel, linker-free, BODIPY-carbohydrate derivatives containing sugar residues at positions C2 and C6 are efficiently obtained by, hitherto unreported, Ferrier-type C-glycosylation of 8- aryl-1,3,5,7-tetramethyl ... -
A Concise Synthesis of a BODIPY-Labeled Tetrasaccharide Related to the Antitumor PI-88
Ventura, Juan; Uriel, Clara; Gómez López, Ana María; Avellanal Zaballa, Edurne; Bañuelos Prieto, Jorge ; García Moreno, Inmaculada; López Pérez, José Cristóbal (MDPI, 2021-05-14)A convergent synthetic route to a tetrasaccharide related to PI-88, which allows the incorporation of a fluorescent BODIPY-label at the reducing-end, has been developed. The strategy, which features the use of 1,2-methyl ... -
A Palette of Efficient and Stable Far-Red and NIR Dye Lasers
Avellanal Zaballa, Edurne; Gartzia Rivero, Leire; Bañuelos Prieto, Jorge ; García Moreno, Inmaculada; Rodríguez Agarrabeitia, Antonia; Peña Cabrera, Eduardo; Ortiz García, María Josefa (MDPI, 2020-09-07)The disposal of long-wavelength-emitting sources is of paramount relevance in technology and biophotonics due to the low interference with the surroundings that these kinds of far-red and near-infrared radiations hold. As ... -
Access to 2,6-Dipropargylated BODIPYs as "Clickable" Congeners of Pyrromethene-567 Dye: Photostability and Synthetic Versatility
Uriel, Clara; Gómez López, Ana María; García Martínez de la Hidalga, Enrique; Bañuelos Prieto, Jorge ; García Moreno, Inmaculada; López Pérez, José Cristóbal (American Chemical Society, 2021-09-03)Hitherto unreported 2,6-dipropargyl-1,3,5,7-tetramethyl BODIPYs can be efficiently prepared by a Nicholas reaction/decomplexation protocol from 1,3,5,7-tetramethyl BODIPYs. The title compounds, which improve the BODIPY ... -
De Novo Access to BODIPY C-Glycosides as Linker-Free Nonsymmetrical BODIPY-Carbohydrate Conjugates
Uriel, Clara; Grenier, Dylan; Herranz, Florian; Casado Antón, Natalia; Bañuelos Prieto, Jorge ; Rebollar, Esther ; García Moreno, Inmaculada; Gómez López, Ana María; López Pérez, José Cristóbal (ACS, 2024-03)Recent years have witnessed an increasing interest in the synthesis and study of BODIPY-glycoconjugates. Most of the described synthetic methods toward these derivatives involve postfunctional modifications of the BODIPY ... -
Development of Geometry-Controlled All-Orthogonal BODIPY Trimers for Photodynamic Therapy and Phototheragnosis
Prieto Castañeda, Alejandro; García Garrido, Fernando; Díaz Norambuena, Carolina; Escriche Navarro, Blanca; García Fernández, Alba; Bañuelos Prieto, Jorge ; Rebollar, Esther ; García Moreno, Inmaculada; Martínez Máñez, Ramón; de la Moya, Santiago; Agarrabeitia, Antonia R.; Ortiz, María J. (American Chemical Society, 2022-05)We have established an easy synthetic protocol for selectively developing all-orthogonal BODIPY trimers with unprece-dented geometries on the basis of selecting methyl oxidation versus electrophilic formylation of key ... -
Polar ammoniostyryls easily converting a clickable lipophilic BODIPY in an advanced plasma membrane probe
Serrano-Buitrago, Sergio; Muñoz-Úbeda, Mónica; Almendro Vedia, Víctor G.; Sánchez-Camacho, Juan; Lora Maroto, Beatriz; Moreno, Florencio; Bañuelos Prieto, Jorge ; García Moreno, Inmaculada; López Montero, Iván; de la Moya, Santiago (RSC, 2023-02-13)A very simple, small and symmetric, but highly bright, photostable and functionalizable molecular probe for plasma membrane (PM) has been developed from an accessible, lipophilic and clickable organic dye based on BODIPY. ... -
Tuning the Photonic Behavior of Symmetrical bis-BODIPY Architectures: The Key Role of the Spacer Moiety
Oliden Sánchez, Ainhoa; Sola Llano, Rebeca; Bañuelos Prieto, Jorge ; García Moreno, Inmaculada; Uriel, Clara; López Pérez, José Cristóbal; Gómez López, Ana María (Frontiers Media, 2019-12)Herein we describe the synthesis, computationally assisted spectroscopy, and lasing properties of a new library of symmetric bridged bis-BODIPYs that differ in the nature of the spacer. Access to a series of BODIPY dimers ...