Browsing by Author "Ortiz de Elguea Flecha, Verónica"
Now showing items 1-3 of 3
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Intramolecular Palladium(II)-catalyzed 6-endo C-H alkenylation directed by the remote N-protecting group. Mechanistic insight and application to the synthesis of dihydroquinolines
Carral Menoyo, Asier; Sotorríos Manrique, Lia; Ortiz de Elguea Flecha, Verónica; Díaz Andrés, Aitor; Sotomayor Anduiza, María Nuria; Gómez Bengoa, Enrique; Lete Expósito, María Esther (American Chemical Society, 2019-12-30)A protocol for the Pd(II)-catalyzed C-H alkenylation reaction of substituted N-allylanilines via an unusual 6-endo process has been developed. A DFT study of the mechanistic pathway has shown that the coordination of the ... -
Palladium-Catalyzed Dehydrogenative Coupling: An Efficient Synthetic Strategy for the Construction of the Quinoline Core
Carral Menoyo, Asier; Ortiz de Elguea Flecha, Verónica; Martínez Nunes, Mikel ; Sotomayor Anduiza, María Nuria; Lete Expósito, María Esther (MDPI, 2017-09)Palladium-catalyzed dehydrogenative coupling is an efficient synthetic strategy for the construction of quinoline scaffolds, a privileged structure and prevalent motif in many natural and biologically active products, in ... -
Pd(II)-Catalyzed Fujiwara-Moritani Reactions for the Synthesis and Functionalization of Substituted Coumarins.
Ortiz de Elguea Flecha, Verónica; Carral Menoyo, Asier; Simón Vidal, Lorena; Martínez Nunes, Mikel ; Barbolla Cuardrado, Iratxe; Lete, Marta G.; Sotomayor Anduiza, María Nuria; Lete Expósito, María Esther (American Chemical Society, 2021-11-09)[EN]Highly substituted coumarins, privileged and versatile scaffolds for bioactive natural products and fluorescence imaging, are obtained via a Pd(II)-catalyzed direct C–H alkenylation reaction (Fujiwara–Moritani reaction), ...