dc.contributor.advisor | Mato, Knez | |
dc.contributor.author | Ashurbekova, Karina | |
dc.date.accessioned | 2023-01-19T10:30:58Z | |
dc.date.available | 2023-01-19T10:30:58Z | |
dc.date.issued | 2022-12-15 | |
dc.date.submitted | 2022-12-15 | |
dc.identifier.uri | http://hdl.handle.net/10810/59361 | |
dc.description | 150 p. | es_ES |
dc.description.abstract | First part of this thesis highlights a new method for obtaining ultrathin conformal films composed of chitin and chitin-based organic-inorganic hybrid biomaterials from the gas phase by molecular layer deposition (MLD). The second part of this thesis investigates silicon-based films with application potential in packaging or further biomedical applications. MLD growth of a new materials group of hybrid alumosilazane films was explored For the first time synthesized from the vapor phase by utilizing a ring-opening reaction of V3N3 and coupling it with TMA was obtained. The last chapter of the thesis reports on the first gas-phase solvent-free synthesis of Polyoxazolines via living cationic ring-opening polymerization. For this a new type of MLD process has been developed, which uses TosCl chloride as initiator for polymerizations of 2-methyl-2-oxazoline, 2-phenyl-2-oxazoline and 2-isopropenyl-2-oxazoline. | es_ES |
dc.description.sponsorship | CICnanoGUNE | es_ES |
dc.language.iso | eng | es_ES |
dc.rights | info:eu-repo/semantics/openAccess | es_ES |
dc.subject | chemical kinetics | es_ES |
dc.subject | interfacial chemistry | es_ES |
dc.subject | reaction mechanics | es_ES |
dc.subject | cinética química | es_ES |
dc.subject | química interfacial | es_ES |
dc.subject | mecánica de reacción | es_ES |
dc.title | Surface Engineering of Biomimetic Antibacterial and Biocompatible Hybrid Materials Through Molecular Layer Deposition. | es_ES |
dc.type | info:eu-repo/semantics/doctoralThesis | es_ES |
dc.rights.holder | (c)2022 KARINA ASHURBEKOVA | |
dc.identifier.studentID | 945694 | es_ES |
dc.identifier.projectID | 21898 | es_ES |
dc.departamentoes | Polímeros y Materiales Avanzados: Física, Química y Tecnología | es_ES |
dc.departamentoeu | Polimero eta Material Aurreratuak: Fisika, Kimika eta Teknologia | es_ES |