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NMR and molecular recognition: The interaction of human galectin-8 and DC-SIGN with natural glycans and glycomimetics.
(2023-03-22)
Glycans are everywhere in Nature, where they play a plethora of functions in every domain of life. The recognition of glycans by lectins is at the heart of a myriad of biological proceses, including host-pathogen interactions, ...
Consecutive Single-Crystal-to-Single-Crystal Isomerization of Novel Octamolybdate Anions within a Microporous Hybrid Framework with Robust Water Sorption Properties
(Wiley, 2023-10)
The 3D hybrid framework [{Cu(cyclam)}3(κ-Mo8O27)] ⋅ 14H2O (1) (cyclam=1,4,8,11-tetraazacyclotetradecane) undergoes sequential single-crystal-to-single-crystal transformations upon heating to afford two different anhydrous ...
H(N3)dap (Hdap = 2,6-Diaminopurine) Recognition by Cu2(EGTA): Structure, Physical Properties, and Density Functional Theory Calculations of [Cu4(μ-EGTA)2(μ-H(N3)dap)2(H2O)2]·7H2O
(MDPI, 2023-08-26)
Reactions in water between the Cu2(µ-EGTA) chelate (EGTA = ethylene-bis(oxyethyleneimino)tetraacetate(4-) ion) and Hdap in molar ratios 1:1 and 1:2 yield only blue crystals of the ternary compound [Cu4(μ-EGTA)2(μ-H(N3)da ...
The role of sample preparation in suspect and non-target screening for exposome analysis using human urine
(Elsevier, 2023-10)
The use of suspect and non-target screening (SNTS) for the characterization of the chemical exposome employing human biofluids is gaining attention. Among the biofluids, urine is one of the preferred matrices since organic ...
Directed C- H Allylation of Aromatic Carboxamides with Allyl Aryl Ethers under Cp*Co(III)-Catalysis
(Wiley-VCH, 2023-11-20)
The Cp*Co(III) C−H allylation of (hetero)arenes with allyl aryl ethers has been developed using an amide as directing group (24 examples). DFT calculations have shed light on the mechanistic course and reactivity pattern, ...
Thermochemical CO2 reduction catalyzed by homometallic and heterometallic nanoparticles generated from the thermolysis o supramolecularly assembled porous metal-adenine precursors
(American Chemical Society, 2023-10-09)
A family of unprecedented supramolecularly assembled porous metal–organic compounds (SMOFs), based on [Cu6M(μ-adeninato)6(μ3-OH)6(μ-H2O)6]2+ cations (MII: Cu, Co, Ni, and Zn) and different dicarboxylate anions (fumarate, ...
Copper(II)-porphyrin functionalized titanium(IV) metal-organic aerogels for the visible-light driven conversion of CO2 to alcohols
(Elsevier, 2023-08)
This manuscript covers the synthesis and characterization of a series of titanium based metal-organic aerogels (MOAs) functionalized with copper(II)-metalated porphyrins for their application in visible-light-driven carbon ...
Trends in Nanoparticles for Leishmania Treatment: A Bibliometric and Network Analysis
(MDPI, 2023-10-28)
Leishmaniasis is a neglected tropical illness with a wide variety of clinical signs ranging
from visceral to cutaneous symptoms, resulting in millions of new cases and thousands of fatalities
reported annually. This ...
Ionic Liquid-Laden Zn-MOF-74-Based Solid-State Electrolyte for Sodium Batteries
(MDPI, 2023-12-12)
Sodium batteries are receiving increasing interest as an alternative to reduce dependence on lithium-based systems. Furthermore, the development of solid-state electrolytes will lead to higher-performing and safer devices. ...
Phase-Stabilization In FAPbI3-Based Perovskite Solar Cells Via Powder Engineering And Additivisation Strategies
(2023-11-22)
The steep rise in greenhouse gas emissions and increasing global energy demand ignited the innovation and implementation of clean and green energy resources such as solar energy. Among the photovoltaics (PV) technologies ...