Search
Now showing items 21-27 of 27
Effect of the change of the ancillary carboxylate bridging ligand on the SMM and luminescence properties of a series of carboxylate-diphenoxido triply bridged dinuclear ZnLn and tetranuclear Zn2Ln2 complexes (Ln = Dy, Er)
(Royal Society of Chemistry, 2018-11-22)
Eleven new dinuclear and tetranuclear compounds of general formulae [Zn(μ-L)(μ-X)Ln(NO3)2]·nS, [Zn2Dy2(μ3-L′)2(μ-sal)2(NO3)(CH3OH)](NO3)·5CH3OH and [Zn2Er2(μ3-L′)2(μ-sal)2(CH3OH)2](NO3)2·4CH3OH (X = benzoate, anthracenate, ...
Influence of Thermally-Induced Structural Transformations over Magnetic and Luminiscence Properties of Tartrate-based Chiral Lanthanide Organic-Frameworks
(RSC, 2020-05-04)
This work reports on the synthesis and characterization of five enantiomeric pairs of isostructural 3D metal-organic
frameworks (MOFs) with the general formula {[Ln2(μ4-tar)2(μ-tar)(H2O)2]·xH2O}n [where Ln(III) = Tb (Tb-L ...
Magneto-thermal properties and slow magnetic relaxation in Mn(II)Ln(III) complexes: Influence of magnetic coupling on the magneto-caloric effect
(2022-08-05)
A family of Mn(II)Ln(III) dinuclear and tetranuclear complexes (Ln = Gd and Dy) has been prepared from the
compartmental ligands N,N’-dimethyl-N,N’-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylenediamine
(H2L1
) and ...
From field-induced to zero-field SMMs associated with open/closed structures of bis(ZnDy) tetranuclear complexes: a combined magnetic, theoretical and optical study
(RSC, 2024-05)
We have prepared a bis(compartmental) Mannich base ligand H4L (1,4,8,11-tetraaza-1,4,8,11-tetrakis(2-hydroxy-3-methoxy-5-methylbenzyl)cyclotetradecane) specifically designed to obtain bis(TMIILnIII) tetranuclear complexes ...
Spin canting and slow magnetic relaxation in mononuclear cobalt(ii) sulfadiazine ternary complexes
(RSC, 2024-01)
Monomeric [Co(SDZ)2phen] (1) and [Co(SDZ)(bq)Cl] (2) complexes (SDZ = sulfadiazine, phen = 1,10-phenanthroline, and bq = 2,2′-biquinoline) have been synthesized and characterized. X-ray diffraction studies indicate that ...
Multifunctional Amino Acid Derivative Coordination Compounds: Novel Contrast Agent and Luminescence Materials
(Wiley, 2024-05)
In this work a family of multidimensional (2-(1H-tetrazol-5-yl)ethyl) amino acid coordination compounds have been synthesized and thoroughly characterized. For this purpose, glycine, valine, phenylalanine and tyrosine have ...
A family of Cd(ii) coordination polymers constructed from 6-aminopicolinate and bipyridyl co-linkers: study of their growth in paper and photoluminescence sensing of Fe3+ and Zn2+ ions
(RSC, 2024-06)
In this work, we report on five novel coordination polymers (CPs) based on the linkage of the [Cd(6apic)2] building block [where 6apic = 6-aminopicolinate] by different bipyridine-type organic spacers, forming different ...