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Now showing items 11-20 of 24
Fe−TPP Coordination Network with Metalloporphyrinic Neutral Radicals and Face-to-Face and Edge-to-Face π−π Stacking
(ACS Publications, 2013-06-25)
Compound ([FeTPPbipy]•)n (TPP = meso-tetraphenylporphyrin and bipy = 4,4′-bipyridine) is the first example of a Fe−TPP−bipy coordination network, and it consists of 1D polymers packed through face-to-face and edge-to-face ...
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
(Elsevier, 2011-08-03)
The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ...
Biomimetic catalysts based on metalloporphyrin MOFs
(2016-04-29)
During the past years, a great effort has been devoted to the anchoring of catalysts into MOFs in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using metalloporphyrins as ...
Crystal structure and characterization of a new μ-oxo bridged iron porphyrin
(2016-04-22)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Ionothermal Synthesis of Cadmium Coordination Polymers: Ionic Liquid Effects on the Synthesis, Structural, and Thermal Characterization
(MDPI, 2019-11-09)
Ionothermal synthesis is a little used method for the preparation of coordination polymers. By this method, two cadmium compounds were synthesized, 1, with formula Cd-3(ox)F-2(Ina)(2) (Ina = isonicotinate) and 2, Cd(NO3)(2)(4,4 ...
Thermal stability and crystallochemical analysis for CoII based coordination polymers with TPP and TPPS porphyrins
(RSC Publishing, 2013-03-16)
Two new CoP–bipy compounds have been synthesised and characterised, where P is TPP for compound 1 (TPP = meso-tetraphenylporphyrin) and TPPS for compound 2 (TPPS = meso-tetraphenylporphinetetrasulfonic
acid tetrasodium ...
Self-assembly of iron TCPP (meso-tetra(4-carboxyphenyl)porphyrin) into a chiral 2D coordination polymer
(Elsevier, 2011-08-16)
Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of high-dimensional coordination polymers. In this work, a new chiral Fe-TCPP (TCPP is ...
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
(RSC Publishing, 2015-01-07)
During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ...
Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives
(RSC Publishing, 2015-05-07)
Compound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-benzenedicarboxylate and DMF is N,N-dimethylformamide) has been synthesized and structurally characterized by X-ray diffraction. It consists of Cu24-clusters ...
Characterization of cobalt based TPP-bipy coordination polymer
(2016-04-22)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...