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Scalable synthetic method for IT-SOFCs compounds
(2016-07-15)
Economically competitive SOFC systems appear ready for commercialization, but
widespread market penetration will require a broad inventory of key starting materials and
fabrication processes to enhance systems and reduce ...
Scalable synthetic method for SOFC compounds
(Elsevier, 2017-09-08)
Although economically competitive SOFC systems seems to be ready for commercialization, a broad inventory of
key starting materials and fabrication processes are needed to enhance systems and reduce costs. These ...
Materiales para su aplicación en celdas SOFCs
(2016-04-12)
Se han sintetizado cinco compuestos (La0.4Sr0.6FeO3, LaNi0.6Fe0.4O3, Zr0.8Y0.2O1.9 , Sm0.2Ce0.8O1.9 y MnCo1.9Fe0.1O4) mediante la técnica de combustión glicina - nitrato (G/N = 1) [1], para su utilización como cátodo, ...
Water-induced phased transformation of a CuII-coordination framework with pyridine-2,5-dicarboxylate and di-2-pyridyl ketone: synchrotron radiation analysis
(The Royal Society of Chemistry, 2015-07-09)
Phase transformations in solid coordination frameworks (SCFs) are of interest for several applications, and this work reports on a crystal-to-crystal transformation found for a CuII-based SCF. Thus, combination of PDC and ...
Highly thermally stable heterogeneous catalysts: study of 0D and 3D porphyrinic MOFs
(The Royal Society of Chemistry, 2017-11-13)
Heterogeneous catalysts are a great bet for green chemistry in many industrial processes and, in the past decade, promising results have been achieved in order to improve the catalytic activity of Metal Organic Frameworks ...
Cationic Mn2+/H+ exchange leading a slow solid-state transformation of a 2D porphyrinic network at ambient conditions
(Elsevier, 2017-03)
Metalloporphyrins exhibit outstanding chemical, physical and biological properties in dissolution, however, it is a challenge to synthesize them as stable solid frameworks. Long-time stability is crucial for future ...
Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
(MDPI, 2015-04-15)
Synthetic metalloporphyrin complexes are often used as analogues of natural
systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ...
Metalloporphyrin-based MOFs: new strategies for catalyst immobilization
(2016-04-25)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Self-assembly of metalloporphyrins: first TPP-bipy coordination polymer with CoII (TPP=meso-tetraphenylporphyrin and bipy=4,4´-bipyridine)
(2015-10-23)
Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ...
Polímeros de Coordinación con Centros Metálicos en Entornos de Coordinación Variables: Posibles Aplicaciones.
(2015-10-08)
El grupo de investigación IMaCris/MaKrisI de la UPV/EHU, atesora una amplia experiencia en el estudio de estructuras metal-orgánicas en diferentes tipos de materiales: • Clústeres y polímeros de coordinación, con conectores ...