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Directed C- H Allylation of Aromatic Carboxamides with Allyl Aryl Ethers under Cp*Co(III)-Catalysis
(Wiley-VCH, 2023-11-20)
The Cp*Co(III) C−H allylation of (hetero)arenes with allyl aryl ethers has been developed using an amide as directing group (24 examples). DFT calculations have shed light on the mechanistic course and reactivity pattern, ...
γ-Substituted Allenic Amides in the Phosphine-Catalyzed Enantioselective Higher Order Cycloaddition with Azaheptafulvenes
(American Chemical Society, 2020-05-28)
Racemic γ-substituted allenes undergo enantioselective higher order [8 + 2]-cycloaddition with azaheptafulvenes using a chiral amino acid derived amidophosphine as catalyst, providing the corresponding azaazulenoid ...
Cp*Co(III)-Catalyzed C−H Hydroarylation of Alkynes and Alkenes and Beyond: A Versatile Synthetic Tool
(ACS, 2020-09-15)
The use of earth-abundant first-row transition
metals, such as cobalt, in C−H activation reactions for the
construction and functionalization of a wide variety of structures
has become a central topic in synthetic ...
Anticipation and modal power: Opening up and closing down the momentum of sociotechnical systems
(Sage, 2022-08-06)
Within STS, there are three approaches to the creation and mobilization of futures: descriptive, normative, and interventive. Visions, expectations, and imaginaries are currently seen as anticipatory artifacts that close ...
Internal friction associated with ε martensite in shape memory steels produced by casting route and through additive manufacturing: Influence of thermal cycling on the martensitic transformation
(Elsevier, 2022-10)
Among the different families of shape memory alloys (SMA), the Fe-Mn-Si-Cr-Ni alloys have attracted a renewed interest because of its low cost, high corrosion resistance and high recovery strength during the shape memory ...
Palladium-mediated synthesis and biological evaluation of C-10b substituted Dihydropyrrolo[1,2-b]isoquinolines as antileishmanial agents
(Elsevier, 2021-04-16)
The development of new molecules for the treatment of leishmaniasis is, a neglected parasitic disease, is
urgent as current anti-leishmanial therapeutics are hampered by drug toxicity and resistance. The pyrrolo[
1,2-b ...
Enacting anticipatory heuristics: a tentative methodological proposal for steering responsible innovation
(Taylor and Francis / Routledge, 2023-01-24)
Over the past decade, various normative frameworks that aim to promote more responsible governance of research and innovation in terms of better aligning with society's demands and expectations have emerged. Among the ...
Fight for Nothing: Fight Club and Nihilism in Capitalist Society
(Uniwersytet im. Adama Mickiewicza w Poznaniu, 2023)
This paper analyses the movie Fight Club (1999) from the philosophical point of view. We reflect on the split personality of the protagonist, showing how the former represents the subject of the modern society, who, unable ...
Dragon Ball on the Basque public TV: influence on viewers’ language attitudes and practices
(Taylor & Francis, 2021-07-01)
Dragon Ball was highly popular among different generations in the Basque Country. The anime TV series was broadcast in Galician, Catalan and Basque practically at the same time in 1990. The translation and dubbing into ...
Basque informal talk increasingly restricted to men: The role of gender in the form of address hika
(DEWS Publication, 2021-03)
Many languages make a T/V distinction when addressing an interlocutor, and Basque also has two main levels of
formality: zuka (formal) and hika (informal). The peculiarity of the Basque informal form of address hika is ...