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A Potassium Metal-Organic Framework based on Perylene- 3,4,9,10-tetracarboxylate as Sensing Layer for Humidity Actuators
(Nature Publishing, 2018-09-26)
We have synthesized a novel three-dimensional metal-organic-framework (MOF) based on the perylene-3,4,9,10-tetracarboxylate linker and potassium as metallic centre. We report the formation of this K-based MOF using ...
Slow Magnetic Relaxation and Luminescent Properties of Mononuclear Lanthanide-Substituted Keggin-Type Polyoxotungstates with Compartmental Organic Ligands
(American Chemical Society, 2022-02-07)
The reaction of mid to late lanthanide ions with the N,N'-dimethyl-N,N'-bis(2-hydroxy-3-formyl-5-bromobenzyl)ethylene-diamine organic ligand and monolacunary Keggin type [alpha-SiW11O39]8- anion affords a series of ...
Exploring the Slow Magnetic Relaxation of a Family of Photoluminescent 3D Lanthanide–Organic Frameworks Based on Dicarboxylate Ligands
(MDPI, 2021-03-16)
A family of metal–organic frameworks with general formula {[Nd2(ant)2((NH2)2-bdc)(DMF)4]·2DMF}n (1) and {[Ln2(ant)2((NH2)2-bdc)(DMF)4]·2DMF·2H2O}n (Ln = Tb (2), Ho (3), and Er (4)) has been obtained from reactions between ...
Designing Single-Molecule Magnets as Drugs with Dual Anti-Inflammatory and Anti-Diabetic Effects
(MDPI, 2020-04-28)
We have designed and synthesized two novel cobalt coordination compounds using bumetanide (bum) and indomethacin (ind) therapeutic agents. The anti-inflammatory effects of cobalt metal complexes with ind and bum were assayed ...
Easy Handling and Cost-Efficient Processing of a Tb3+-MOF: The Emissive Capacity of the Membrane-Immobilized Material, Water Vapour Adsorption and Proton Conductivity
(MDPI, 2022-12-08)
The development of convenient, non-complicated, and cost-efficient processing techniques for packing low-density MOF powders for industry implementation is essential nowadays. To increase MOFs’ availability in industrial ...
Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions
(MDPI, 2023-02-15)
As a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·H2O}n chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic ...
Koordinazio polimero luminiszenteak: gailu argitsuen etorkizuna
(Servicio Editorial de la Universidad del País Vasco/Euskal Herriko Unibertsitatearen Argitalpen Zerbitzua, 2020)
Luminescent coordination polymers have been known since the previous century, but have undergone significant growth from the past decade up to now thanks to their unique ability to emit light. Based on these materials, a ...
Luminescence and Magnetic Properties of Two Three -Dimensional Terbium and Dysprosium MOFs Based on Azobenzene-4,4 '-Dicarboxylic Linker
(MDPI, 2016-02)
We report the in situ formation of two novel metal-organic frameworks based on terbium and dysprosium ions using azobenzene-4,4-dicarboxylic acid (H(2)abd) as ligand, synthesized by soft hydrothermal routes. Both materials ...
Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks
(MDPI, 2022-11-13)
The present work reports on a detailed discussion about the synthesis, characterization, and luminescence properties of three pairs of enantiopure 3D metal–organic frameworks (MOFs) with general formula {[Ln2(L/D-tart)3( ...
Modulation of Pore Shape and Adsorption Selectivity by Ligand Functionalization in a Series of “rob”-like Flexible Metal-Organic Frameworks
(RSC, 2018-08-08)
We report the synthesis of a new family of four new isoreticular metal–organic frameworks (MOFs) based on
Cu–Cu paddle-wheel building units. The four MOFs contain 1D microchannels modulated by chemical
functionalisation ...