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Open and closed forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O cationic coordination polymer: magnetic properties and high pressure CO2/CH4 gas sorption.
(The Royal Society of Chemistry, 2018-01-21)
Two closed and one open structural forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O (H2Tae= 1,1,2,2-tetraacetylethane, Bpa= 1,2-Bis(4-pyridyl)ethane) cationic coordination polymer have been synthesized. Three ...
Stability study of MOF@IL composite materials
(2017-03)
Metal-organic frameworks (MOF) offer unique advantages for many applications due to their
ordered structures, high thermal stability, tunable chemical functionality, ultra-high porosity and
the availability of hundreds ...
Ionic liquids in the control of the poly(vinylidene fluoride-co-hexafluoropropylene) membranes morphology
(2017-12-13)
The development of polymer membranes with tailored micro-morphology and wettability are a demand in the areas of filtration, sensors or tissue engineering, among others. Poly(vinylidene fluoride-co-hexafluoropropylene) ...
Ionic liquids in the control of the poly(vinylidene fluoride-co- hexafluoropropylene) membranes morphology [Poster]
(2017-10-27)
The development of polymer membranes with tailored micro-morphology and wettability are a demand in the areas of filtration, sensors or tissue engineering, among others. Poly(vinylidene fluoride-co-hexafluoropropylene) ...
MOF@IL composite materials as Pd(II) supports for heterogeneous organocatalytic reactions
(2018-07-24)
Metal-Organic Frameworks (MOFs) have experienced a rapid emerge in the last two decades because they offer unique advantages for many applications due to their ordered structures, high thermal stability, tunable chemical ...
Modulation of the Bifunctional CrVI to CrIII Photoreduction and Adsorption Capacity in ZrIV and TiIV Benchmark Metal-Organic Frameworks
(MDPI, 2021-01-01)
The presence of hexavalent chromium water pollution is a growing global concern. Among the currently applied technologies to remove CrVI, its adsorption and photocatalytic reduction to CrIII less mobile and toxic forms are ...
Water-induced phased transformation of a CuII-coordination framework with pyridine-2,5-dicarboxylate and di-2-pyridyl ketone: synchrotron radiation analysis
(The Royal Society of Chemistry, 2015-07-09)
Phase transformations in solid coordination frameworks (SCFs) are of interest for several applications, and this work reports on a crystal-to-crystal transformation found for a CuII-based SCF. Thus, combination of PDC and ...
Highly thermally stable heterogeneous catalysts: study of 0D and 3D porphyrinic MOFs
(The Royal Society of Chemistry, 2017-11-13)
Heterogeneous catalysts are a great bet for green chemistry in many industrial processes and, in the past decade, promising results have been achieved in order to improve the catalytic activity of Metal Organic Frameworks ...
Cationic Mn2+/H+ exchange leading a slow solid-state transformation of a 2D porphyrinic network at ambient conditions
(Elsevier, 2017-03)
Metalloporphyrins exhibit outstanding chemical, physical and biological properties in dissolution, however, it is a challenge to synthesize them as stable solid frameworks. Long-time stability is crucial for future ...
Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
(MDPI, 2015-04-15)
Synthetic metalloporphyrin complexes are often used as analogues of natural
systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ...