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Catalytic performance of a new 1D Cu(II) coordination polymer {Cu(NO3)(H2O)}(HTae)(4,4'-Bpy)
(2017-03)
There has been extensive interest in the synthesis and design of new porous coordination
polymers [1] because of their potential applicability in different areas. One interesting crystal
engineering approach to construct ...
Functionalization of Cu3BTC2@IL composites with Pd(II) for catalytic applications
(2017-10-29)
Metal-organic frameworks could be excellent supports for active catalytic species in order to obtain heterogeneous and reusable catalysts, easily removable from the reaction media.[1,2] Additionally, the presence of ...
Composite beta-AgVO3@V5+1.6V4+0.4O4.8 hydrogels and xerogels for catalytic applications
(2016-04-07)
Silver vanadium oxides and vanadium oxides, and concretely β-AgVO3 phase, have received considerable attention in the last decade due to their unique physical and chemical properties, including electrochemical and ...
Vanadyl arsenates as catalysts for selective oxidation of organic sulfides and alkenes
(Elsevier, 2010-12-09)
Two vanadyl arsenates templated with ethylendiamonium (EnVAs) and piperazonium (PipVAs) were evaluated as catalysts for the oxidation of thioethers and alkenes, using H2O2 and t-butyl hydroperoxide (TBHP) as oxidants. The ...
MOF@IL composite materials as Pd(II) supports for heterogeneous organocatalytic reactions
(2018-07-24)
Metal-Organic Frameworks (MOFs) have experienced a rapid emerge in the last two decades because they offer unique advantages for many applications due to their ordered structures, high thermal stability, tunable chemical ...
M(C6H16N3)2(VO3)4 as heterogeneous catalysts. Study of three new hybrid vanadates of cobalt(II), nickel(II) and copper(II) with 1-(2-aminoethyl)piperazonium.
(Royal Society of Chemistry, 2011-10-14)
Three new hybrid vanadates have been synthesized under hydrothermal conditions with the formula M(C6H16N3)2(VO3)4, where M= Co(II), Ni(II) and Cu(II). The structural analyses show that the phases are isostructural and ...
Biomimetic catalysts based on metalloporphyrin MOFs
(2016-04-29)
During the past years, a great effort has been devoted to the anchoring of catalysts into MOFs in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using metalloporphyrins as ...
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
(RSC Publishing, 2015-01-07)
During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ...
Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)
(2016-04-29)
Solid Coordination Frameworks (SCFs) have been widely explored on different catalytic reactions, and during the past years metalloporphyrins have been investigating in order to mimick it in the solid state their natural ...