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Catalytic performance of a new 1D Cu(II) coordination polymer {Cu(NO3)(H2O)}(HTae)(4,4'-Bpy)
(2017-03)
There has been extensive interest in the synthesis and design of new porous coordination
polymers [1] because of their potential applicability in different areas. One interesting crystal
engineering approach to construct ...
Functionalization of Cu3BTC2@IL composites with Pd(II) for catalytic applications
(2017-10-29)
Metal-organic frameworks could be excellent supports for active catalytic species in order to obtain heterogeneous and reusable catalysts, easily removable from the reaction media.[1,2] Additionally, the presence of ...
Composite beta-AgVO3@V5+1.6V4+0.4O4.8 hydrogels and xerogels for catalytic applications
(2016-04-07)
Silver vanadium oxides and vanadium oxides, and concretely β-AgVO3 phase, have received considerable attention in the last decade due to their unique physical and chemical properties, including electrochemical and ...
Catalytic Performance of a New 1D Cu(II) Coordination Polymer {Cu(NO3)(H2O)}(HTae)(4,40-Bpy) for Knoevenagel Condensation
(MDPI, 2016-12-01)
The {Cu(NO3)(H2O)}(HTae)(4,40-Bpy) (H2Tae = 1,1,2,2-tetraacetylethane, 4,40-Bpy =
4,40-Dipyridyl) 1D coordination polymer has been obtained by slow evaporation. The crystal structure
consists of parallel and oblique ...
Vanadyl arsenates as catalysts for selective oxidation of organic sulfides and alkenes
(Elsevier, 2010-12-09)
Two vanadyl arsenates templated with ethylendiamonium (EnVAs) and piperazonium (PipVAs) were evaluated as catalysts for the oxidation of thioethers and alkenes, using H2O2 and t-butyl hydroperoxide (TBHP) as oxidants. The ...
Hydrothermal Synthesis and Study of Inorganic-Organic Hybrid Vanadate of Nickel(II) Coordination Complex with Pyrazine, Ni3(C4H4N2)3(V8O23)
(Elsevier, 2011-02-25)
The three-dimensional hybrid compound Ni3(C4H4N2)3(V8O23) has been synthesized by mild hydrothermal methods under autogenous pressure at 170 ºC, together with another hybrid phase, Ni2(C4H4N2)(V4O12)(H2O)2. The isolation ...
Structural Transformations in the Thermal Dehydration of [Cu2(bpa)(btec)(H2O)4]n Coordination Polymer
(MDPI, 2019-05-13)
Reactions between pyridinic ligands such as 1,2-bis(4-pyridyl)ethane (bpa) and transition metal cations are a very widespread technique to produce extended coordination polymers such as Metal-Organic Frameworks. In combination ...
Crystal structure of K0.75[FeII 3.75FeIII 1.25(HPO3)6]- 0.5H2O, an open-framework iron phosphite with mixed-valent FeII/FeIII ions
(International Union of Crystallography, 2016)
Single crystals of the title compound, potassium hexaphosphitopentaferrate(
II,III) hemihydrate, K0.75[FeII
3.75FeIII
1.25(HPO3)6] 0.5H2O, were grown
under mild hydrothermal conditions. The crystal structure is isotypic ...
Open and closed forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O cationic coordination polymer: magnetic properties and high pressure CO2/CH4 gas sorption.
(The Royal Society of Chemistry, 2018-01-21)
Two closed and one open structural forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O (H2Tae= 1,1,2,2-tetraacetylethane, Bpa= 1,2-Bis(4-pyridyl)ethane) cationic coordination polymer have been synthesized. Three ...
Stability study of MOF@IL composite materials
(2017-03)
Metal-organic frameworks (MOF) offer unique advantages for many applications due to their
ordered structures, high thermal stability, tunable chemical functionality, ultra-high porosity and
the availability of hundreds ...