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Intramolecular Palladium(II)-catalyzed 6-endo C-H alkenylation directed by the remote N-protecting group. Mechanistic insight and application to the synthesis of dihydroquinolines
(American Chemical Society, 2019-12-30)
A protocol for the Pd(II)-catalyzed C-H alkenylation reaction of substituted N-allylanilines
via an unusual 6-endo process has been developed. A DFT study of the mechanistic pathway has shown
that the coordination of the ...