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Hydrogen Tunneling in Catalytic Hydrolysis and Alcoholysis of Silanes
(Wiley, 2022-09-05)
[EN] An unprecedented quantum tunneling effect has been observed in catalytic Si-H bond activations at room temperature. The cationic hydrido-silyl-iridium(III) complex, {Ir[SiMe(o-C6H4SMe)(2)](H)(PPh3)(THF)}[BAr4F], has ...
Polyethylene Oxide/Sodium Sulfonamide Polymethacrylate Blends as Highly Conducting Single-Ion Solid Polymer Electrolytes
(American Chemical Society, 2023-04)
In this work, blends of polyethylene oxide (PEO) and poly(sodium 1-[3-(methacryloyloxy)propylsulfonyl]-1-(trifluoromethanesulfonyl) imide) (PNaMTFSI) in different compositions were investigated for their application as ...
Crosslinking versus interdiffusion in two pot one pack acetoacetoxy-amine based binder system
(Elsevier, 2023-01)
A two-pot-one-pack waterborne crosslinking system is studied by following the crosslinking and interdiffusion between the polymer particles functionalized with acetoacetoxy on one hand and with polyethyleneimine on the ...
Polymer Colloids: Current Challenges, Emerging Applications, and New Developments
(American Chemical Society, 2023-03)
Polymer colloids are complex materials that have the potential to be used in a vast array of applications. One of the main reasons for their continued growth in commercial use is the water-based emulsion polymerization ...
Single-Ion Conducting Polymer Nanoparticles as Functional Fillers for Solid Electrolytes in Lithium Metal Batteries
(American Chemical Society, 2021-11-03)
[EN]Composite solid electrolytes including inorganic nanoparticles or nanofibers which improve the performance of polymer electrolytes due to their superior mechanical, ionic conductivity, or lithium transference number ...
Influence of Tartrate Ligand Coordination over Luminescence Properties of Chiral Lanthanide-Based Metal–Organic Frameworks
(MDPI, 2022-11-13)
The present work reports on a detailed discussion about the synthesis, characterization, and luminescence properties of three pairs of enantiopure 3D metal–organic frameworks (MOFs) with general formula {[Ln2(L/D-tart)3( ...
Lactide-caprolactone copolymers with tuneable barrier properties for packaging applications
(Elsevier, 2020-06-07)
Lactide-caprolactone copolymers have been synthetized employing two metallic catalysts, Ph3Bi and SnOct2. The analysis of the microstructure by NMR reveals that gradient like copolymers are obtained with SnOct2 catalyst, ...
Printable Single-Ion Polymer Nanoparticle Electrolytes for Lithium Batteries
(Wiley, 2024-03)
New material solutions are searched for the manufacturing and safety of current batteries. Herein, an extrusion printable polymer separator for lithium batteries based on single-ion polymer electrolytes is presented. The ...
Making Room for Silicon: Including SiOx in a Graphite-Based Anode Formulation and Harmonization in 1 Ah Cells
(MDPI, 2024-03-28)
Transitioning to more ambitious electrode formulations facilitates developing high-energy density cells, potentially fulfilling the demands of electric car manufacturers. In this context, the partial replacement of the ...
Degradable Alternating Copolymers by Radical Copolymerization of 2-Methylen-1,3-dioxepane and Crotonate Esters
(ACS, 2024-03)
Producing backbone degradable copolymers via free-radical copolymerization is a promising, yet challenging method to develop more sustainable materials for many applications. In this work, we present the copolymerization ...