BackSearch
Now showing items 1-6 of 6
Self-assembly of metallated TPP porphyrin by external dipyridyl ligands
(2015-10-23)
Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ...
Coordination and crystallisation molecules: Their interactions affecting the dimensionality of metalloporphyrinic SCFs
(MDPI (Multidisciplinary Digital Publishing Institute) Basel, Switzerland, 2015-04-15)
Synthetic metalloporphyrin complexes are often used as analogues of natural
systems, and they can be used for the preparation of new Solid Coordination Frameworks (SCFs). In this work, a series of six metalloporphyrinic ...
Self-assembly of metalloporphyrins: first TPP-bipy coordination polymer with CoII (TPP=meso-tetraphenylporphyrin and bipy=4,4´-bipyridine)
(2015-10-23)
Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ...
Water-induced phased transformation of a CuII-coordination framework with pyridine-2,5-dicarboxylate and di-2-pyridyl ketone: synchrotron radiation analysis
(The Royal Society of Chemistry, 2015-07-09)
Phase transformations in solid coordination frameworks (SCFs) are of interest for several applications, and this work reports on a crystal-to-crystal transformation found for a CuII-based SCF. Thus, combination of PDC and ...
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
(RSC Publishing, 2015-01-07)
During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ...
Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives
(RSC Publishing, 2015-05-07)
Compound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-benzenedicarboxylate and DMF is N,N-dimethylformamide) has been synthesized and structurally characterized by X-ray diffraction. It consists of Cu24-clusters ...