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Characterization of cobalt based TPP-bipy coordination polymer
(2016-04-22)
Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ...
Dehydration for a solid coordination network based on CuII-(py)2C(OH)2 trimers
(2016-04-22)
Materials consisting of metal ions or clusters that are linked by polyfunctional organic ligands form networks
of different dimensionalities. Their structural features, including large cavities and high surface areas, ...
Metalloporphyrin-based MOFs: First Cobalt Based TPPS-bipy Coordination Network
(2016-04-22)
Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ...
Theoretical and experimental absorption spectra study of [(FeTPPbipy]·)n provided by TD-DFT calculations
(2016-04-29)
Iron metalloporphyrins are paradigmatic examples of nanodevices used by natural systems like haemoglobin or cytochromes in oxygen transport, electron transfer and catalysis. Therefore, they can be thought to be developed ...
Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)
(2016-04-29)
Solid Coordination Frameworks (SCFs) have been widely explored on different catalytic reactions, and during the past years metalloporphyrins have been investigating in order to mimick it in the solid state their natural ...
Synthesis of new Ln4(Al2O6F2)O2 (Ln = Sm,Eu,Gd) phases with a cuspidine-related structure
(International Union of Crystallography, 2019-01)
The first fluorination of the cuspidine-related phases of Ln4(Al2O7□)O2 (where Ln = Sm, Eu, Gd) is reported. A low-temperature reaction with poly(vinylidene difluoride) lead to the fluorine being substituted in place of ...