Browsing OpenAire by Author "Safari, Maryam"
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Biodegradable binary blends of poly (butylene succinate) or poly (ε-caprolactone) with poly (butylene succinate-ran-ε-caprolactone) copolymers: Crystallization behavior
Safari, Maryam; Pérez Camargo, Ricardo Arpad; Ballester Bayarri, Laura; Mugica Iztueta, Miren Agurtzane; Zubitur Soroa, María Manuela; Wang, Dujin; Müller Sánchez, Alejandro Jesús ; Liu, Guoming (Elsevier, 2022-08-12)Poly (butylene succinate) (PBS) and polycaprolactone (PCL) are two immiscible biocompatible and biodegradable polymers. Aiming to combine the properties of these biodegradable polymers, this work explores for the first ... -
Controlling the Isothermal Crystallization of Isodimorphic PBS-ran-PCL Random Copolymers by Varying Composition and Supercooling
Safari, Maryam; Mugica Iztueta, Miren Agurtzane; Zubitur Soroa, María Manuela; Martínez de Ilarduya, Antxon; Muñoz-Guerra, Sebastián; Müller Sánchez, Alejandro Jesús (MDPI, 2019-12-20)In this work, we study for the first time, the isothermal crystallization behavior of isodimorphic random poly(butylene succinate)-ran-poly(ε-caprolactone) copolyesters, PBS-ran-PCL, previously synthesized by us. We perform ... -
Crystallization of isodimorphic aliphatic random copolyesters: pseudo-eutectic behavior and double-crystalline materials
Pérez Camargo, Ricardo Arpad; Arandia, Idoia; Safari, Maryam; Cavallo, Dario; Lotti, Nadia; Soccio, Michelina; Müller Sánchez, Alejandro Jesús (Elservier, 2018-02-28)Isodimorphic random copolyesters are intriguing polymeric materials that can crystallize in their entire composition range, despite the random distribution of comonomer units along their chains. This behavior stems from ... -
Effect of Nanoconfinement on the isodimorphic crystallization of Poly(butylene succinate-ran-caprolactone) Random Copolymers
Safari, Maryam; Leon Boigues, Laia; Shi, Guangyu; Maiz, Jon; Liu, Guoming; Wang, Dujin; Mijangos, Carmen; Müller Sánchez, Alejandro Jesús (ACS, 2020-07-21)In this paper, we study for the first time the effect of hard confinement on the isodimorphic crystallization of random copolyesters. A series of poly(butylene succinate-ran-caprolactone) samples encompassing the entire ... -
How Confinement Affects the Nucleation, Crystallization, and Dielectric Relaxation of Poly(butylene succinate) and Poly(butylene adipate) Infiltrated within Nanoporous Alumina Templates
Safari, Maryam; Maiz, Jon; Shi, Guangyu; Juanes, Diana; Liu, Guoming; Wang, Dujin; Mijangos, Carmen; Alegría Loinaz, Angel María ; Müller Sánchez, Alejandro Jesús (ACS Publications, 2019-10-17)This work describes the successful melt infiltration of poly(butylene succinate) (PBS) and poly(butylene adipate) (PBA) within 70 nm diameter anodic aluminum oxide (AAO) templates. The infiltrated samples were characterized ... -
Nanostructural Organization of Thin Films Prepared by Sequential Dip-Coating Deposition of Poly(Butylene Succinate), Poly(ε-Caprolactone) and Their Copolyesters (PBS-ran-PCL)
Peñas Núñez, Mario Iván; Ocando, Connie; Penott Chang, Evis; Safari, Maryam; Ezquerra, Tiberio A.; Rebollar, Esther ; Nogales, Aurora; Hernández, Rebeca; Müller Sánchez, Alejandro Jesús (Elsevier, 2021-06-04)In this work, we prepare and characterize multiphasic thin films containing poly(epsilon-caprolactone), PCL, poly (butylene succinate), PBS, and a poly (butylene succinate-ran-epsilon-caprolactone) (PBS-ran-PCL) random ... -
Synthesis, Structure, Crystallization and Mechanical Properties of Isodimorphic PBS-ran-PCL Copolyesters
Safari, Maryam; Otaegi Tena, Itziar ; Aramburu Ocáriz, Nora ; Guerrica Echevarría Estanga, Gonzalo María ; Martínez de Ilarduya, Antxon; Sardon Muguruza, Haritz; Müller Sánchez, Alejandro Jesús (MDPI, 2021-07-09)Isodimorphic behavior is determined by partial inclusion of comonomer segments within the crystalline structure and arises from the comparatively similar repeating chain units of the parental homopolymers. Isodimorphic ...