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An Uncertainty Principle for Solutions of the Schrödinger Equation on H-Type Groups
(Cambridge University Press, 2020-04-02)
In this paper we consider uncertainty principles for solutions of certain partial differential equations on H -type groups. We first prove that, on H -type groups, the heat kernel is an average of Gaussians in the central ...
Iron-Catalyzed Direct α-Arylation of Ethers with Azoles
(Royal Society of Chemistry, 2015-07-14)
The direct α-arylation of cyclic and acyclic ethers with azoles has been achieved, which features a novel iron-catalyzed cross-dehydrogenative coupling (CDC) process. This practical oxidative method allowed the efficient ...
Graphene as Vehicle for Ultrafast Lithium Ion Capacitor Development Based on Recycled Olive Pit Derived Carbons
(Electrochemical Society, 2019-08-21)
Herein we report a series of lithium ion capacitors (LICs) with extraordinary energy-to-power ratios based on olive pit recycled carbons and supported on graphene as a conducting matrix. LICs typically present limited ...
Polygenic contribution to the relationship of loneliness and social isolation with schizophrenia
(Nature Research, 2022-01-10)
[EN] Previous research suggests an association of loneliness and social isolation (LNL-ISO) with schizophrenia. Here, we demonstrate a LNL-ISO polygenic score contribution to schizophrenia risk in an independent case-control ...
A fluorogenic cyclic peptide for imaging and quantification of drug-induced apoptosis
(Nature, 2020-08-12)
Programmed cell death or apoptosis is a central biological process that is dysregulated in many diseases, including inflammatory conditions and cancer. The detection and quantification of apoptotic cells in vivo is hampered ...
Ultrasonic Guided Wave Testing on Cross-Ply Composite Laminate: An Empirical Study
(MDPI, 2020-09-16)
Structural health monitoring comprises a set of techniques to detect defects appearing in structures. One of the most viable techniques is based on the guided ultrasonic wave test (UGWT), which consists of emitting waves ...
Unprecedented Multicomponent Organocatalytic Synthesis of Propargylic Esters via CO2 Activation
(Wiley‐VCH, 2019-02-19)
An efficient and straightforward organocatalytic method for the
direct, multicomponent carboxylation of terminal alkynes with
CO2 and organochlorides, towards propargylic esters, is reported
for the first time. ...
Manganese-Catalyzed Multicomponent Synthesis of Tetrasubstituted Propargylamines: System Development and Theoretical Study
(Wiley-VCH, 2020-07-20)
The importance of multicomponent reactions as an efficient tool in organic synthesis is widely recognized, as the need for sustainable, practical, atom- and step-economic methodologies is becoming a crucial concept in ...
Methodologically Grounded SemanticAnalysis of Large Volume of Chilean Medical Literature Data Applied to the Analysis of Medical Research Funding Efficiency in Chile
(BioMed Central, 2020-09-29)
Background Medical knowledge is accumulated in scientific research papers along time. In order to exploit this knowledge by automated systems, there is a growing interest in developing text mining methodologies to extract, ...
An umpolung strategy to react catalytic enols with nucleophiles
(Nature, 2019-11-20)
The selective synthesis of a-functionalized ketones with two similar enolizable positions can be accomplished using allylic alcohols and iridium(III) catalysts. A formal 1,3-hydrogen shift on allylic alcohols generates ...