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Opportunities for organocatalysis in polymer synthesis via step-growth methods
(Elservier, 2019-03-14)
Organocatalysis has emerged as an invaluable tool for polymer synthesis and has already demonstrated versatility for replacing organometallic catalysts in many polymerization reactions. The overall ease of removal and lower ...
Room temperature synthesis of non-isocyanate polyurethanes (NIPUs) using highly reactive N-substituted 8-membered cyclic carbonates
(RSC, 2016-02-16)
There is a growing interest to develop green synthetic pathways towards industrially relevant polymers
such as polyurethanes without the use of toxic and dangerous isocyanate monomers. The most promising
route towards ...
Unexpected Synthesis of Segmented Poly(hydroxyurea−urethane)s from Dicyclic Carbonates and Diamines by Organocatalysis
(ACS, 2018-07-17)
A complete study of the effect of different organocatalysts on the step-growth polyaddition of a five-membered
dicyclic carbonate, namely diglycerol dicarbonate, with a poly(ethylene glycol)-based diamine in bulk at 120 ...
Non-Isocyanate Polyurethane Soft Nanoparticles Obtained by Surfactant-Assisted Interfacial Polymerization
(ACS, 2017-01-24)
Polyurethanes (PUs) are considered ideal candidates for drug delivery applications due to their easy synthesis, excellent mechanical properties, and biodegradability. Unfortunately, methods for preparing well-defined PU ...