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Comb-like acrylic-based polymer latexes containing nano-sized crystalline or liquid crystalline domains
(2016-06-13)
Conventional (meth)acrylate polymer latexes have been widely used for coatings, adhesives, paper and textile finishes, cement additives and other applications. These polymers exhibit useful properties such as adhesion to ...
Water-borne coatings and pressure-sensitive adhesives produced with polymerizable surfactants.
(2016-06-09)
Nowadays, solvent-borne coatings and pressure-sensitive adhesives (PSAs) are still widely used in the industry. However, environmental regulations favor the elimination of solvents, and as a consequence, acrylic water-borne ...
Precise characterization and modeling of particle morphology development in emulsion polymerization.
(2019-07-04)
This PhD aimed at paving the way to process optimization and on-line control of particle morphology in emulsion polymerization process. The bottleneck in achieving this goal is the lack of proper device for on-line monitoring ...
Synthesis of hydrophilic polymers with comb structure by free radical copolymerization for cementitious formulations.
(2019-07-24)
Superplasticizers are nowadays one of the most important constituents of modern concrete. They have generally been used to decrease the viscosity of cement suspensions or to reduce the amount of mixing water necessary, ...
Development of waterborne polymeric dispersions based on biobased monomers for their application as PSAs and coatings
(2020-07-21)
Since few years ago, environmental concerns are pushing up the society towards the use of renewable sources as solution to reduce the carbon footprint in our daily consumer goods such as coatings or adhesives. In this ...
Innovative Poly(3,4-ethylenedioxythiophene) materials for electrochemical energy storage
(2017-04-21)
Conducting polymers, such as poly(3,4-ethylenedioxythiophene) (PEDOT), are attractive materials to be implemented in energy storage devices due to their easy processing, high conductivity, light weight and good electrochemical ...
Late transition metal silyl and acyl complexes through E-H activation: reactivity and catalytic applications
(2019-09-13)
Se han sintetizado tres ligandos multidentados tipo silil-tioeter para la obtención de silil- o hidrurosilil- complejos de rodio e iridio mediante activación del enlace Si-X (siendo X = H o C), y el posterior estudio de ...
Chiral-at-metal Iridium(III) Complexes Containing Dithienylethene-Based Photoswitchable Ligands
(2022-03-18)
El objetivo principal de este proyecto de investigación es el desarrollo de nuevos complejos organometálicos fotosensibles basados en ligandos DTE para la síntesis de compuestos quirales en el (chiral-at-metal), mostrando ...
Surface enhanced Raman scattering (SERS) bioimaging of complex 3D cellu-lar systems
(2022-06-17)
Esta tesis se ha centrado en la dispersión Raman mejorada en superficie (SERS) como técnica de bioimagen, en particular para la observación de sistemas biológicos tridimensionales (3D) de células tumorales. Para esta ...
Copper Homeostasis in the Filamentous Ascomycete Aspergillus nidulans.
(2021-04-07)
El objetivo de esta tesis doctoral ha sido el estudio de la homeostasis del cobre en el hongo filamentoso Aspergillus nidulans. El cobre es un oligoelemento necesario para la vida, pero en cantidades superiores a las ...