Browsing Artículos, Comunicaciones, Libros by Author "Macgregor, Stuart A."
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Stability and C–H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism
Krämer, Tobias; Bustos Rosas, Itxaso; Sinclair, Matthew J. G.; Gyton, Matthew R.; Tan, Sze-yin; Wedge, Christopher J.; Macgregor, Stuart A.; Chaplin, Adrian B. (ACS, 2023-06-15)One-electron oxidation of palladium(0) and platinum(0) bis(phosphine) complexes enables isolation of a homologous series of linear d9 metalloradicals of the form [M(PR3)2]+ (M = Pd, Pt; R = tBu, Ad), which are stable in ...