Zerrendatu IMaCris / MaKrisI ikerketa taldea honen arabera: izenburua
62-tik 37-56 emaitza erakusten
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Metalloporphyrin-based MOFs: First Cobalt Based TPPS-bipy Coordination Network
(2016-04-22)Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ... -
Metalloporphyrin-based MOFs: new strategies for catalyst immobilization
(2016-04-25)Metalloporphyrin systems are one of the cornerstones on which the existence of life is based, as major biochemical, enzymatic and photochemical functions depend on the special properties of the tetrapyrrolic macrocycle. ... -
Metodologías Sintéticas para la Obtención de Compuestos de Coordinación Metal-Orgánicos
(2016-04-25)La síntesis de compuestos híbridos orgánicos-inorgánicos o metal-organic framework (MOF) ha atraído un interés especial durante las últimas dos décadas, debido a la posibilidad de obtener una gran variedad de estructuras ... -
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
(Elsevier, 2011-08-03)The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ... -
MOFs basados en CuII-PDC-bpe (PDC= 2,5-piridindicarboxilato, bpe= 1,2-di(4piridil)eteno): Cristaloquímica de redes 2D tipo Herringbone
(2016-04-29)Los sólidos de coordinación (SCF), también conocidos como Metal Organic Frameworks (MOFs), han desarrollado un gran avance en la última década debido a la posibilidad de obtener una gran variedad de estructuras cristalinas ... -
MOFS metaloporfirínicos 1D y 2D: Estudio cristaloquímico
(2016-05-02)Los sistemas metaloporfirínicos son piezas clave en el engranaje de la vida, debido a las propiedades bioquímicas, enzimáticas y fotoquímicas que desempeña el macrociclo tetrapirrólico presente en las porfirinas. Las ... -
MOFs metaloporfirínicos: biomimetizando sus propiedades naturales
(2016-04-29)Las metaloporfirinas son moléculas biológicas que desempeñan un papel fundamental en multitud de procesos biológicos. Uno de los retos actuales consiste en trasladar la actividad catalítica que presentan a sistemas ... -
MOFs porosos: “Tallando” el espacio en arquitecturas supramoleculares
(2016-04-14)Los MOFs (metal-organic-frameworks) están siendo objeto de un gran interés, muy especialmente por su gran versatilidad en la obtención de estructuras abiertas; es decir, con cavidades o poros estratégicamente diseñados ... -
Mother structures related to the hexagonal and cubic close packing in Cu24 clusters: solvent-influenced derivatives
(RSC Publishing, 2015-05-07)Compound 1 [Cu24(m BDC)24(DMF)20(H2O)4]• 24DMF•40H2O (m-BDC is 1,3-benzenedicarboxylate and DMF is N,N-dimethylformamide) has been synthesized and structurally characterized by X-ray diffraction. It consists of Cu24-clusters ... -
Nuevas cromitas de composición La1-xMxCr0.9Ni0.1O3(M=Sr, ND, Ca; x<0.3) con tamaño de A y desorden fijados, para su uso como ánodos de pilas SOFCs
(2016-06-24)El desarrollo de nuevos materiales y la optimización de las técnicas de fabricación son claves para conseguir reducir la temperatura de operación, y con ello, el coste, de sistemas de generación de energía como las pilas ... -
Open and closed forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O cationic coordination polymer: magnetic properties and high pressure CO2/CH4 gas sorption.
(The Royal Society of Chemistry, 2018-01-21)Two closed and one open structural forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O (H2Tae= 1,1,2,2-tetraacetylethane, Bpa= 1,2-Bis(4-pyridyl)ethane) cationic coordination polymer have been synthesized. Three ... -
Optimization of the large scale synthesis of the LSF-20 cathode material for SOFCs
(2016-06-24)Solid oxide fuel cells (SOFCs) have the potential to be one of the cleanest and most efficient energy technologies for direct conversion of chemical fuels to electricity. Economically competitive SOFC systems appear poised ... -
Polímeros de Coordinación con Centros Metálicos en Entornos de Coordinación Variables: Posibles Aplicaciones.
(2015-10-08)El grupo de investigación IMaCris/MaKrisI de la UPV/EHU, atesora una amplia experiencia en el estudio de estructuras metal-orgánicas en diferentes tipos de materiales: • Clústeres y polímeros de coordinación, con conectores ... -
Scalable synthetic method for IT-SOFCs compounds
(2016-07-15)Economically competitive SOFC systems appear ready for commercialization, but widespread market penetration will require a broad inventory of key starting materials and fabrication processes to enhance systems and reduce ... -
Scalable synthetic method for SOFC compounds
(Elsevier, 2017-09-08)Although economically competitive SOFC systems seems to be ready for commercialization, a broad inventory of key starting materials and fabrication processes are needed to enhance systems and reduce costs. These ... -
Self-assembly of iron TCPP (meso-tetra(4-carboxyphenyl)porphyrin) into a chiral 2D coordination polymer
(Elsevier, 2011-08-16)Synthetic metalloporphyrin complexes are often used as analogues of natural systems, and they can be used for the preparation of high-dimensional coordination polymers. In this work, a new chiral Fe-TCPP (TCPP is ... -
Self-assembly of metallated TPP porphyrin by external dipyridyl ligands
(2015-10-23)Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ... -
Self-assembly of metalloporphyrins: first TPP-bipy coordination polymer with CoII (TPP=meso-tetraphenylporphyrin and bipy=4,4´-bipyridine)
(2015-10-23)Supramolecular entities based on self-assembly of metalloporphyrins are paradigmatic examples of the great efficiency of the nanodevices used by natural systems in photosynthesis, oxygen transport, electron transfer and ... -
SOFC development at CNH2
(2018-07)Solid oxide fuel cells (SOFC´s) are devices that convert chemical energy from reactants into heat and electricity with high efficiency. Usually, these systems operate at high temperatures (600-1000ºC) and are able to run ... -
Stability study of MOF@IL composite materials
(2017-03)Metal-organic frameworks (MOF) offer unique advantages for many applications due to their ordered structures, high thermal stability, tunable chemical functionality, ultra-high porosity and the availability of hundreds ...