Browsing Grupo de investigación IMaCris / MaKrisI by Author "Serrano Larrea, Edurne"
Now showing items 1-20 of 20
-
Biomimetic catalysts based on metalloporphyrin MOFs
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Iglesias, Marta; Arriortua Marcaida, María Isabel (2016-04-29)During the past years, a great effort has been devoted to the anchoring of catalysts into MOFs in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using metalloporphyrins as ... -
Catalytic performance of a new 1D Cu(II) coordination polymer {Cu(NO3)(H2O)}(HTae)(4,4'-Bpy)
Serrano Larrea, Edurne; Fernández de Luis, Roberto; Iglesias, Marta; Arriortua Marcaida, María Isabel (2017-03)There has been extensive interest in the synthesis and design of new porous coordination polymers [1] because of their potential applicability in different areas. One interesting crystal engineering approach to construct ... -
Catalytic Performance of a New 1D Cu(II) Coordination Polymer {Cu(NO3)(H2O)}(HTae)(4,40-Bpy) for Knoevenagel Condensation
Serrano Larrea, Edurne; Fernández de Luis, Roberto; Arriortua Marcaida, María Isabel (MDPI, 2016-12-01)The {Cu(NO3)(H2O)}(HTae)(4,40-Bpy) (H2Tae = 1,1,2,2-tetraacetylethane, 4,40-Bpy = 4,40-Dipyridyl) 1D coordination polymer has been obtained by slow evaporation. The crystal structure consists of parallel and oblique ... -
Composite beta-AgVO3@V5+1.6V4+0.4O4.8 hydrogels and xerogels for catalytic applications
Serrano Larrea, Edurne; Fernández de Luis, Roberto; Iglesias, Marta; Arriortua Marcaida, María Isabel (2016-04-07)Silver vanadium oxides and vanadium oxides, and concretely β-AgVO3 phase, have received considerable attention in the last decade due to their unique physical and chemical properties, including electrochemical and ... -
Crystal structure of K0.75[FeII 3.75FeIII 1.25(HPO3)6]- 0.5H2O, an open-framework iron phosphite with mixed-valent FeII/FeIII ions
Serrano Larrea, Edurne; Mesa Rueda, José Luis; Legarra Sáez, Estíbaliz ; Aguayo Urquijo, Andrés Tomás ; Arriortua Marcaida, María Isabel (International Union of Crystallography, 2016)Single crystals of the title compound, potassium hexaphosphitopentaferrate( II,III) hemihydrate, K0.75[FeII 3.75FeIII 1.25(HPO3)6] 0.5H2O, were grown under mild hydrothermal conditions. The crystal structure is isotypic ... -
Encapsulation of β-alanine model amino-acid in zirconium(IV) metal organic frameworks: Defect engineering to improve host guest interactions
Rodríguez Muguruza, Asier; Fernández de Luis, Roberto; Iglesias, Naroa; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone (Elsevier, 2020-04)Metal-Organic Frameworks (MOFs) are porous coordination networks assembled through metal complexes with organic linkers. Due to their chemical versatility, these materials are being investigated for various applications ... -
Functionalization of Cu3BTC2@IL composites with Pd(II) for catalytic applications
Metal-organic frameworks could be excellent supports for active catalytic species in order to obtain heterogeneous and reusable catalysts, easily removable from the reaction media.[1,2] Additionally, the presence of ... -
Heterogeneous catalytic activity on Mn, Fe and Co-based metalloporphyrinic Solid Coordination Frameworks (SCFs)
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Iglesias, Marta; Arriortua Marcaida, María Isabel (2016-04-29)Solid Coordination Frameworks (SCFs) have been widely explored on different catalytic reactions, and during the past years metalloporphyrins have been investigating in order to mimick it in the solid state their natural ... -
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Iglesias, Marta; Lezama Diago, Luis María; Arriortua Marcaida, María Isabel (RSC Publishing, 2015-01-07)During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ... -
Hydrothermal Synthesis and Study of Inorganic-Organic Hybrid Vanadate of Nickel(II) Coordination Complex with Pyrazine, Ni3(C4H4N2)3(V8O23)
Serrano Larrea, Edurne; Mesa Rueda, José Luis; Arriortua Marcaida, María Isabel (Elsevier, 2011-02-25)The three-dimensional hybrid compound Ni3(C4H4N2)3(V8O23) has been synthesized by mild hydrothermal methods under autogenous pressure at 170 ºC, together with another hybrid phase, Ni2(C4H4N2)(V4O12)(H2O)2. The isolation ... -
Ionic liquids in the control of the poly(vinylidene fluoride-co- hexafluoropropylene) membranes morphology [Poster]
GSaiz, Paula; Lopes, Ana Catarina; Eizagirre, Simone; Fernández de Luis, Roberto; Serrano Larrea, Edurne; Fidalgo Marijuan, Arkaitz; Arriortua Marcaida, María Isabel (2017-10-27)The development of polymer membranes with tailored micro-morphology and wettability are a demand in the areas of filtration, sensors or tissue engineering, among others. Poly(vinylidene fluoride-co-hexafluoropropylene) ... -
M(C6H16N3)2(VO3)4 as heterogeneous catalysts. Study of three new hybrid vanadates of cobalt(II), nickel(II) and copper(II) with 1-(2-aminoethyl)piperazonium.
Serrano Larrea, Edurne; Mesa Rueda, José Luis; Pizarro Sanz, José Luis ; Iglesias, Marta; Rojo Aparicio, Teófilo ; Arriortua Marcaida, María Isabel (Royal Society of Chemistry, 2011-10-14)Three new hybrid vanadates have been synthesized under hydrothermal conditions with the formula M(C6H16N3)2(VO3)4, where M= Co(II), Ni(II) and Cu(II). The structural analyses show that the phases are isostructural and ... -
Materiales de tipo MOF orientados a la adsorción de contaminantes y catálisis heterogénea. Nuevas perspectivas.
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Amayuelas López, Eder ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Fernández de Luis, Roberto; Arriortua Marcaida, María Isabel (2017-11-22)Nuestro grupo de investigación cuenta con una amplia experiencia en la síntesis y caracterización de materiales multifuncionales basados en redes de coordinación porosas de tipo MOF (metal-organic framework). La estrategia ... -
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
Berrocal Torres, Teresa; Mesa Rueda, José Luis; Serrano Larrea, Edurne; Bazán Blau, Begoña del Pilar ; Pizarro Sanz, José Luis ; Lezama Diago, Luis María; Rojo Aparicio, Teófilo ; Arriortua Marcaida, María Isabel (Elsevier, 2011-08-03)The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ... -
MOFs metaloporfirínicos: biomimetizando sus propiedades naturales
Fidalgo Marijuan, Arkaitz; Barandika Argoitia, Miren Gotzone ; Bazán Blau, Begoña del Pilar ; Urtiaga Greaves, Miren Karmele ; Serrano Larrea, Edurne; Iglesias, Marta; Arriortua Marcaida, María Isabel (2016-04-29)Las metaloporfirinas son moléculas biológicas que desempeñan un papel fundamental en multitud de procesos biológicos. Uno de los retos actuales consiste en trasladar la actividad catalítica que presentan a sistemas ... -
Open and closed forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O cationic coordination polymer: magnetic properties and high pressure CO2/CH4 gas sorption.
Fernández de Luis, Roberto; Serrano Larrea, Edurne; Orive Gómez de Segura, Joseba; Fidalgo Marijuan, Arkaitz; Lezama Diago, Luis María; Arriortua Marcaida, María Isabel (The Royal Society of Chemistry, 2018-01-21)Two closed and one open structural forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O (H2Tae= 1,1,2,2-tetraacetylethane, Bpa= 1,2-Bis(4-pyridyl)ethane) cationic coordination polymer have been synthesized. Three ... -
Polímeros de Coordinación con Centros Metálicos en Entornos de Coordinación Variables: Posibles Aplicaciones.
Serrano Larrea, Edurne; Fernández de Luis, Roberto; Fidalgo Marijuan, Arkaitz; Llano Tomé, Francisco; Amayuelas López, Eder ; Bravo García, Laura ; Bazán Blau, Begoña del Pilar ; Barandika Argoitia, Miren Gotzone ; Urtiaga Greaves, Miren Karmele ; Arriortua Marcaida, María Isabel (2015-10-08)El grupo de investigación IMaCris/MaKrisI de la UPV/EHU, atesora una amplia experiencia en el estudio de estructuras metal-orgánicas en diferentes tipos de materiales: • Clústeres y polímeros de coordinación, con conectores ... -
Stability study of MOF@IL composite materials
Serrano Larrea, Edurne; Fernández de Luis, Roberto; Fidalgo Marijuan, Arkaitz; Martínez-Doñate, Ander; González-Santacruz, Nicolás; Lopes, Ana Catarina; Arriortua Marcaida, María Isabel (2017-03)Metal-organic frameworks (MOF) offer unique advantages for many applications due to their ordered structures, high thermal stability, tunable chemical functionality, ultra-high porosity and the availability of hundreds ... -
Structural Transformations in the Thermal Dehydration of [Cu2(bpa)(btec)(H2O)4]n Coordination Polymer
Bravo García, Laura ; Serrano Larrea, Edurne; Artetxe Arretxe, Beñat; Lezama Diago, Luis María; Gutiérrez Zorrilla López, Juan Manuel ; Arriortua Marcaida, María Isabel (MDPI, 2019-05-13)Reactions between pyridinic ligands such as 1,2-bis(4-pyridyl)ethane (bpa) and transition metal cations are a very widespread technique to produce extended coordination polymers such as Metal-Organic Frameworks. In combination ... -
Vanadyl arsenates as catalysts for selective oxidation of organic sulfides and alkenes
Berrocal Torres, Teresa; Serrano Larrea, Edurne; Iglesias, Marta; Arriortua Marcaida, María Isabel (Elsevier, 2010-12-09)Two vanadyl arsenates templated with ethylendiamonium (EnVAs) and piperazonium (PipVAs) were evaluated as catalysts for the oxidation of thioethers and alkenes, using H2O2 and t-butyl hydroperoxide (TBHP) as oxidants. The ...