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Catalytic Performance of a New 1D Cu(II) Coordination Polymer {Cu(NO3)(H2O)}(HTae)(4,40-Bpy) for Knoevenagel Condensation
(MDPI, 2016-12-01)
The {Cu(NO3)(H2O)}(HTae)(4,40-Bpy) (H2Tae = 1,1,2,2-tetraacetylethane, 4,40-Bpy =
4,40-Dipyridyl) 1D coordination polymer has been obtained by slow evaporation. The crystal structure
consists of parallel and oblique ...
Vanadyl arsenates as catalysts for selective oxidation of organic sulfides and alkenes
(Elsevier, 2010-12-09)
Two vanadyl arsenates templated with ethylendiamonium (EnVAs) and piperazonium (PipVAs) were evaluated as catalysts for the oxidation of thioethers and alkenes, using H2O2 and t-butyl hydroperoxide (TBHP) as oxidants. The ...
Hydrothermal Synthesis and Study of Inorganic-Organic Hybrid Vanadate of Nickel(II) Coordination Complex with Pyrazine, Ni3(C4H4N2)3(V8O23)
(Elsevier, 2011-02-25)
The three-dimensional hybrid compound Ni3(C4H4N2)3(V8O23) has been synthesized by mild hydrothermal methods under autogenous pressure at 170 ºC, together with another hybrid phase, Ni2(C4H4N2)(V4O12)(H2O)2. The isolation ...
Structural Transformations in the Thermal Dehydration of [Cu2(bpa)(btec)(H2O)4]n Coordination Polymer
(MDPI, 2019-05-13)
Reactions between pyridinic ligands such as 1,2-bis(4-pyridyl)ethane (bpa) and transition metal cations are a very widespread technique to produce extended coordination polymers such as Metal-Organic Frameworks. In combination ...
Crystal structure of K0.75[FeII 3.75FeIII 1.25(HPO3)6]- 0.5H2O, an open-framework iron phosphite with mixed-valent FeII/FeIII ions
(International Union of Crystallography, 2016)
Single crystals of the title compound, potassium hexaphosphitopentaferrate(
II,III) hemihydrate, K0.75[FeII
3.75FeIII
1.25(HPO3)6] 0.5H2O, were grown
under mild hydrothermal conditions. The crystal structure is isotypic ...
Open and closed forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O cationic coordination polymer: magnetic properties and high pressure CO2/CH4 gas sorption.
(The Royal Society of Chemistry, 2018-01-21)
Two closed and one open structural forms of the interpenetrated [Cu2(Tae)(Bpa)2](NO3)2•nH2O (H2Tae= 1,1,2,2-tetraacetylethane, Bpa= 1,2-Bis(4-pyridyl)ethane) cationic coordination polymer have been synthesized. Three ...
Mild Hydrothermal Synthesis, Crystal Structure, Thermal Behavior, Spectroscopic and Magnetic Properties of (NH4)0.80Li0.20[Fe(AsO4)F]
(Elsevier, 2011-08-03)
The (NH4)0.80Li0.20[Fe(AsO4)F] compound has been synthesized under mild hydrothermal conditions. The compound crystallize in the orthorhombic Pna21 space group, with cell parameters a= 13.352(9), b= 6.7049(9), c= 10.943(2) ...
M(C6H16N3)2(VO3)4 as heterogeneous catalysts. Study of three new hybrid vanadates of cobalt(II), nickel(II) and copper(II) with 1-(2-aminoethyl)piperazonium.
(Royal Society of Chemistry, 2011-10-14)
Three new hybrid vanadates have been synthesized under hydrothermal conditions with the formula M(C6H16N3)2(VO3)4, where M= Co(II), Ni(II) and Cu(II). The structural analyses show that the phases are isostructural and ...
Encapsulation of β-alanine model amino-acid in zirconium(IV) metal organic frameworks: Defect engineering to improve host guest interactions
(Elsevier, 2020-04)
Metal-Organic Frameworks (MOFs) are porous coordination networks assembled through
metal complexes with organic linkers. Due to their chemical versatility, these materials are
being investigated for various applications ...
Heterogeneous catalytic properties of unprecedented m-O-[FeTCPP]2 dimers (H2TCPP = meso-tetra(4-carboxyphenyl)porphyrin): unusual superhyperfine EPR structure
(RSC Publishing, 2015-01-07)
During the past years, a great effort has been devoted to the anchoring of catalysts into solid coordination networks in order to achieve heterogeneous catalysts. In this sense, an innovative approach consists on using the ...